445424-75-9

Upstream product

• 867-13-0 diethoxyphosphoryl-acetic acid ethyl ester 
• 131085-31-9 5-((tert-butyldiphenylsilyl)oxy)pentan-2-one 
• 215251-69-7 4-(tert-butyldiphenylsilyloxy)-N-methoxy-N-methylbutanamide 

Downstream Products

• 1193752-64-5 ethyl 6-(tert-butyldiphenylsilyloxy)-3,3-dimethylhexanoate 
• 1207538-76-8 C₂₅H₃₆O₂Si 
• 1207538-89-3 C₂₅H₃₄O₂Si 
• 445424-78-2 3-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-3-methyl-pent-4-en-1-ol 
• 445424-80-6 tert-butyl-(4-methyl-4-vinyl-hex-5-enyloxy)-diphenyl-silane 
• 445425-10-5 Trimethyl-((R)-4-methyl-4-vinyl-cyclohex-2-enyloxy)-silane 
• 445425-11-6 (R)-4-Methyl-4-vinyl-cyclohex-2-enol 
• 445424-76-0 6-((tert-butyldiphenylsilyl)oxy)-3-methylhex-2-en-1-ol 

Relevant academic research and scientific papers

Diastereoselective ring-closing metathesis for the construction of a quaternary carbon stereogenic center

A diastereoselective ring-closing metathesis of the trienes 1 leading to the formation of a quaternary carbon stereogenic center on the cyclohexenes 2 has been developed.

Efficient one-to-one coupling of easily available 1,3-dienes with carbon dioxide

An efficient one-to-one coupling reaction of atmospheric pressure carbon dioxide with 1,3-dienes is realized for the first time through PSiP-pincer type palladium-catalyzed hydrocarboxylation. The reaction is applicable to various 1,3-dienes including easily available chemical feedstock such as 1,3-butadiene and isoprene. This protocol affords a highly useful method for the synthesis of β,γ-unsaturated carboxylic acid derivatives from CO2.

Synthetic studies toward neovibsanins A and B: construction of the neovibsanin core utilizing palladium(0)-catalyzed carbonylative cyclization with carbon monoxide

The core A-ring of neovibsanins A (1) and B (2), which are potent neurotrophic agents isolated from the leaves of Viburnum awabuki, have been effectively constructed by the intramolecular palladium(0)-catalyzed carbonylative cyclization of alkenyl iodide