445468-00-8Relevant academic research and scientific papers
Mg-Promoted Double Silylation of Trifluoroacetimidoyl Chlorides. A New Entry to the Fluorinated Dianion Equivalents
Kobayashi, Takeshi,Nakagawa, Takashi,Amii, Hideki,Uneyama, Kenji
, p. 4297 - 4300 (2003)
(Equation presented) A Mg(0)/Me3SiCl system was found to be effective for the preparation of a novel fluorinated dianion equivalent. A one-pot reaction sequence involving reductive C-F and C-Cl bond cleavage reactions of trifluoroacetimidoyl ch
An improved synthesis of fluorinated imidoylsilanes
Akamatsu, Chie,Yamauchi, Atsushi,Kobayashi, Takeshi,Ozeki, Yu,Takagi, Jun,Amii, Hideki,Uneyama, Kenji
, p. 1836 - 1840 (2007/10/03)
A practical and efficient method for the preparation of fluorinated imidoylsilanes is described. The key step involves finely controlled activation of C-Cl and C-Br bonds in fluorinated imidoyl chlorides and bromides, respectively. Georg Thieme Verlag Stu
