4468-73-9Relevant academic research and scientific papers
Selective demethylation ofO-aryl glycosides by iridium-catalyzed hydrosilylation
Jones, Caleb A. H.,Schley, Nathan D.
supporting information, p. 5953 - 5956 (2021/06/18)
The cleavage of alkyl ethers by hydrosilylation is a powerful synthetic tool for the generation of silyl ethers. Previous attempts to apply this transformation to carbohydrate derivatives have been constrained by poor selectivity and preferential reductio
The catalytic synthesis of aryl O-glycosides using triaryloxyboranes
Yamanoi, Takashi,Yamazaki, Ippo
, p. 4009 - 4011 (2007/10/03)
Triaryloxyboranes worked as highly reactive glycosyl acceptors of glycosyl acetates to afford aryl O-glycosides in excellent yields. A catalytic amount of ytterbium(III) trifluoromethanesulfonate activated the formation reaction of aryl O-glycosidic linka
The Photochemistry of Ketones derived from Carbohydrates. Part 9. Formation of O- and C-Ribofuranoside Derivatives by Photodecarbonylation of O-and C-Glycosides of lyxo-Hexopyranos-4-ulose Derivatives
Collins, Peter M.,Travis, Anthony S.
, p. 779 - 786 (2007/10/02)
The syntheses of 6-deoxy-2,3-O-isopropylidene-α-L-lyxo-hexopyranosyl-4-ulose-ethane (7) and -benzene (8), and the assignment of their anomeric configurations by 1H and 13C n.m.r. spectroscopy, are described.The preparations of a number of O-glycosid-4-ulo
