1095-03-0

Basic information

• Product Name: TRIPHENYL BORATE
• Synonyms: Boric acid triphenyl;Orthoboric acid triphenyl ester;Triphenoxyborane;tris(phenoxy)borane;Boron Triphenoxide;NSC 806;Triphenoxyboron;Boric Acid Triphenyl Ester Phenyl Borate
• CAS NO: 1095-03-0
• Molecular Formula: C₁₈H₁₅BO₃
• Molecular Weight: 290.12
• EINECS: 214-137-0
• Product Categories: Boronic Acids and Derivatives;Organoborates;Organometallic Reagents;Aromatics;Boron Derivatives;Inhibitors;Intermediates & Fine Chemicals;Pharmaceuticals;Boron compounds;B (Classes of Boron Compounds);Boric Acid Esters;Boric Acid Triesters
• Mol File: 1095-03-0.mol
• Article Data: 60

Chemical Properties

• Melting Point: 98-101 °C(lit.)
• Boiling Point: 158°C/0.05mmHg(lit.)
• Flash Point: 113.4oC
• Appearance: /Solid
• Density: 1.135 g/cm³
• Vapor Pressure: 0.000142mmHg at 25°C
• Refractive Index: 1.572
• Storage Temp.: Hygroscopic, Refrigerator, Under Inert Atmosphere
• Solubility: Soluble in chloroform, methanol.
• Sensitive: Moisture Sensitive
• CAS DataBase Reference: TRIPHENYL BORATE(CAS DataBase Reference)
• NIST Chemistry Reference: TRIPHENYL BORATE(1095-03-0)
• EPA Substance Registry System: TRIPHENYL BORATE(1095-03-0)

Safety Data

• Hazard Codes: F,T
• Statements: 11-23/24/25-41
• Safety Statements: 16-26-36/37/39-45
• RIDADR: UN 2811 6.1/PG 3
• WGK Germany: 3
• RTECS: ED5775000
• HazardClass: 6.1
• PackingGroup: Ⅲ
• Hazardous Substances Data: 1095-03-0(Hazardous Substances Data)

Usage

Chemical Properties

White Solid

Uses

An organoborane compound with chemosterilant activity against Cochliomyia hominivorax (screwworm flies). Triphenyl Borate can be used as a competitive inhibitor of urease of Klebsiella aerogenes used to study the mechanisms of interaction with the nickel active site.

Uses

Triphenyl borate is a useful boronic ester with chemosterilant activity against Cochliomyia hominivorax. It is also used as a competitive inhibitor of urease of Klebsiella aerogenes used to study the mechanisms of interaction with the nickel active site.

Synthesis Reference(s)

The Journal of Organic Chemistry, 43, p. 2731, 1978 DOI: 10.1021/jo00407a051

InChI:InChI=1/C18H15BO3/c1-4-10-16(11-5-1)20-19(21-17-12-6-2-7-13-17)22-18-14-8-3-9-15-18/h1-15H

Upstream product

• 109502-94-5 5-chloro-7-nitro-3,3-diphenyl-3H-4,1,2-benzoxadiazine 
• 109-50-2 3-Hexyn-2-ol 
• 1095019-75-2 2-Chloro-5-[(2-ethyl-1-piperidinyl)sulfonyl]-aniline 
• 1095019-40-1 [2-(2-Ethyl-1-piperidinyl)-3-pyridinyl]methanamine 
• 1095010-50-6 2-bromo-4-cyclopropylthiazole 
• 1095010-49-3 Ethyl 1-Cbz-5-Hydroxypiperidine-3-carboxylate 
• 1095010-48-2 1-Boc-5-Hydroxypiperidine-3-carboxylic Acid 
• 1095010-47-1 1,3-Piperidinedicarboxylic acid, 5-hydroxy-, 1-(1,1-dimethylethyl) 3-methyl ester 
• 1095010-46-0 1-Cbz-5-Hydroxypiperidine-3-carboxylic Acid 
• 1095010-45-9 Methyl 1-Cbz-5-Hydroxypiperidine-3-carboxylate 
• 1095010-44-8 Methyl 5-Hydroxypiperidine-3-carboxylate 
• 1095010-43-7 N-(4-Methylsulphonyl-3-nitrophenyl)piperazine 
• 1095010-42-6 N-(5-Methylsulphonyl-2-nitrophenyl)piperazine 
• 1095010-36-8 6-Bromo-4-Methylquinoline-3-carboxylic acid 

Downstream Products

• 1095030-20-8 N-ethyl-N-methyl-beta-alanine(SALTDATA: HCl) 
• 1095036-68-2 4-Bromo-2-butoxybenzoic acid 
• 109503-77-7 3-{[4-(diethylamino)phenyl]imino}-1,3-dihydro-2H-indol-2-one 
• 1095039-92-1 2-(2-Ethyl-1-piperidinyl)-5-fluoroaniline 
• 1095-04-1 triphenyl trithiophosphite 
• 1095059-79-2 N-(4-azepan-1-ylbenzyl)-N-methylamine 
• 109506-39-0 2-(1-oxa-4-azoniacyclohex-4-yl)ethoxy-phenyl-methanethione chloride 
• 109506-57-2 2-(3,4-DIHYDRO-2H-1,5-BENZODIOXEPIN-7-YL)ETHANAMINE 
• 1095070-62-4 N-methyl-N-[4-(3-methylpiperidin-1-yl)benzyl]amine 
• 109507-07-5 N-(3-chlorophenyl)-N~3~,N~3~-diethyl-beta-alaninamide hydrochloride 
• 109507-19-9 1,1-dimethyl-4-(phenylcarbonyl)piperazin-1-ium iodide 
• 1095080-29-7 IFLAB-BB F1670-0186 
• 1095080-54-8 1-Ethylpyrazole-5-boronic Acid 
• 1095085-73-6 3-(2-ethoxyethoxy)benzonitrile 

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Alkyl- and phenyl-substituted borate anion receptors, triphenyl borate (TPB) and trimethyl borate (TMB), are investigated as electrolyte additives in lithium ion batteries (LiFePO4 cathode, 1 M LiPF6 EC-DMC 1:1 electrolyte) at 25 and 60 °C. TPB shows formation of a thick surface/electrolyte int...detailed

TRIPHENYL BORATE (cas 1095-03-0) as a bi-functional additive to improve surface stability of Ni-rich cathode material08/13/2019

Nickel-rich cathode material has received marked attention as an advanced cathode material, however, its inferior surface property limits the achievement of high performance in lithium-ion batteries. We propose the use of a bi-functional additive of triphenyl borate (TPB) for improvement of the ...detailed

TRIPHENYL BORATE (cas 1095-03-0) catalyzed synthesis of amides from carboxylic acids and amines08/12/2019

Herein we report triphenyl borate as a new catalyst for synthesis of amides by catalytic condensation of carboxylic acids and amines. Our protocol is applicable for synthesis of wide range of amides furnishing excellent yields up to 92%. In addition developed method requires low catalyst loading...detailed