450374-35-3Relevant academic research and scientific papers
Reversible intramolecular hydride transfer between tantalum and an aromatic ring: An η5-cyclohexadienyl complex as a masked hydride
Gavenonis, John,Tilley, T. Don
, p. 8536 - 8537 (2002)
The methyl triflate complex (2,6-Mes2C6H3N=)(2,6-Mes2C6H3NH)TaMe(OSO2CF3) reacts cleanly with H2 to give the η5-cyclohexadienyl complex 3. Comple
Tantalum alkyl and silyl complexes of the bulky (terphenyl)imido ligand
Gavenonis, John,Tilley, T. Don
, p. 5549 - 5563 (2008/10/08)
Tantalum alkyl and silyl complexes of the bulky (terphenyl)imido ligand were investigated. Terphenyl ligands were employed extensively for the stabilization of highly reactive main group species. The TaMe2 group was identified by a 1H nuclear magnetic resonance (NMR) at -0.41 ppm and a 13C NMR resonance at 57.5 ppm.
