4511-39-1

Usage

Uses

Used in Plastics Industry:
TERT-AMYL PEROXYBENZOATE 90 is used as a polymerization initiator for the production of various types of plastics, enabling the formation of polymer chains and improving the material's properties.
Used in Resin Industry:
TERT-AMYL PEROXYBENZOATE 90 is used as a cross-linking agent in the production of resins, promoting the formation of a three-dimensional network structure and enhancing the resin's mechanical strength and chemical resistance.
Used in Rubber Industry:
TERT-AMYL PEROXYBENZOATE 90 is used as a polymerization initiator in the production of rubbers, facilitating the formation of rubber polymers and improving the rubber's elasticity and durability.
Used in Organic Synthesis:
TERT-AMYL PEROXYBENZOATE 90 is used as a reagent in the synthesis of various organic compounds, acting as a source of reactive oxygen species and promoting oxidation reactions.
Safety Precautions:
When handling TERT-AMYL PEROXYBENZOATE 90, it is essential to wear protective clothing, goggles, and gloves to minimize the risk of skin and eye irritation. Additionally, proper ventilation should be ensured in the work area to prevent the accumulation of hazardous fumes.

InChI:InChI=1/C12H16O3/c1-4-12(2,3)15-14-11(13)10-8-6-5-7-9-10/h5-9H,4H2,1-3H3

Upstream product

• 3425-61-4 tert-amyl hydroperoxide 
• 98-88-4 benzoyl chloride 
• 75-85-4 tert-Amyl alcohol 
• 65-85-0 benzoic acid 

Downstream Products

• 4160-52-5 1-(4-methylphenyl)butan-1-one 
• 95971-74-7 N-(1-phenylbutyl)acetamide 

Relevant academic research and scientific papers

Iron-Catalyzed Dehydrative Alkylation of Propargyl Alcohol with Alkyl Peroxides to Form Substituted 1,3-Enynes

This paper reports a new method for the generation of substituted 1,3-enynes, whose synthesis by other methods could be a challenge. The dehydrative decarboxylative cascade coupling reaction of propargyl alcohol with alkyl peroxides is enabled by an iron catalyst and alkylating reagents. Primary, secondary, and tertiary alkyl groups can be introduced into 1,3-enynes, affording various substituted 1,3-enynes in moderate to good yields. Mechanistic studies suggest the involvement of a radical-polar crossover pathway.

Alkyl radical triggered: In situ SO2-capture cascades

An unprecedented in situ SO2-capture cascade triggered by alkyl radicals has been documented herein. Mechanistic investigations suggest that, triggered by alkyl radicals, SO2 was released in situ and subsequently fixed into polycyclic small molecules. A wide range of alkylsulfonyl substituted polycyclic compounds were easily prepared with high yields and good functional group tolerability.

Iron-Catalyzed Decarboxylative Alkyl Etherification of Vinylarenes with Aliphatic Acids as the Alkyl Source

Because of the lack of effective alkylating reagents, alkyl etherification of olefins with general alkyl groups has not been previously reported. In this work, a variety of alkyl diacyl peroxides and peresters generated from aliphatic acids have been found to enable the first iron-catalyzed alkyl etherification of olefins with general alkyl groups. Primary, secondary and tertiary aliphatic acids are suitable for this reaction, delivering products with yields up to 97 %. Primary and secondary alcohols react well, affording products in up to 91 % yield.