4518-00-7

Basic information

• Product Name: Phenol, 2-(1,7,7-trimethylbicyclo[2.2.1]hept-2-yl)-, exo-
• CAS NO: 4518-00-7
• Molecular Formula: C16H22O
• Molecular Weight: 230.35
• Mol File: 4518-00-7.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Phenol, 2-(1,7,7-trimethylbicyclo[2.2.1]hept-2-yl)-, exo-(CAS DataBase Reference)
• NIST Chemistry Reference: Phenol, 2-(1,7,7-trimethylbicyclo[2.2.1]hept-2-yl)-, exo-(4518-00-7)
• EPA Substance Registry System: Phenol, 2-(1,7,7-trimethylbicyclo[2.2.1]hept-2-yl)-, exo-(4518-00-7)

Safety Data

• Hazardous Substances Data: 4518-00-7(Hazardous Substances Data)

Upstream product

• 1380095-62-4 2-((1R,2S,4S)-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl)phenyl (1S,4R)-4,7,7-trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carboxylate 
• 79-92-5 camphene 
• 177698-19-0 Beta-pinene 
• 15086-27-8 aluminium(III) phenoxide 
• 565-00-4 dl-camphene 
• 108-95-2 phenol 
• 18172-67-3 beta-pinene 
• 7785-70-8 (+)-α-pinene 
• 736109-58-3 1,7,7-trimethyl-bicyclo[2.2.1]heptan-2-one 
• 578-57-4 2-bromoanisole 

Downstream Products

• 58315-90-5 2-isobornyl-4-nitrophenol 
• 1243572-61-3 2-hydroxy-3-(1,7,7-trimethylbiyclo[2.2.1]hept-exo-2-yl)benzaldehyde 
• 128-39-2 2,6-di-tert-butylphenol 
• 58508-15-9 2-isobornyl-4-bromophenol 

Relevant articles and documents

Aluminum phenoxide-promoted alkylation of phenol with α- And β-pinenes

Alkylation of phenol with natural α- and β-pinenes in the presence of Al(OPh)3 gives the O- and C-alkylation products with the structurally different terpene fragments. The terpenophenols obtained have proved to be optically active.

Alkylation of phenol by β-pinene in the presence of aluminum phenolate

The alkylation of phenol by β-pinene using Al(OPh)3 as a catalyst was studied. It was found that the composition of the products depended on the ratio of starting materials. The principal products were chromane-type ethers with an equimolar ratio of starting materials and an excess of phenol. ortho-Alkylated phenol and an ether with a terpene substituent of bornyl structure were formed with a two-fold excess of β-pinene.

Separation of racemic ortho-isobornylphenol into enantiomers and evaluation of their antioxidant activity

Racemic ortho-isobornylphenol was separated into enantiomers through diastereomeric camphanates. The absolute configuration of chiral centers of the isolated products was determined by X-ray studies. Antioxidant activity and membrane-protective properties