4537-61-5Relevant academic research and scientific papers
Novel diaryl sulfonium salt compound containing diphenylethene groups as well as preparation method and application thereof
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Paragraph 0061-0063; 0067; 0068, (2018/09/13)
The invention relates to the technical field of new material organic chemicals, and particularly relates to a novel diaryl sulfonium salt shown as a formula (I) and having a diphenylethene conjugatedstructure, a chemical process preparation technique ther
Trimethylsilyl halide-promoted Michaelis-Arbuzov rearrangement
Renard, Pierre-Yves,Vayron, Philippe,Mioskowski, Charles
, p. 1661 - 1664 (2007/10/03)
(Matrix presented) We describe a new, straightforward, and easy-to-handle method for achieving an unprecedented trimethylsilyl halide-catalyzed Michaelis-Arbuzov-like rearrangement. This rearrangement occurs at temperatures from room temperature to 80°C and does not require addition of any alkyl halide. The scope and limitations of this new reaction are explored, as well as its mechanism.
