186818-96-2

Upstream product

• 100-42-5 styrene 
• 104-95-0 (4-bromophenyl)thioanisole 
• 1449-46-3 benzyltriphenylphosphonium bromide 
• 3446-89-7 4-(Methylthio)benzaldehyde 
• 4537-61-5 diethyl benzylphosphonate 
• 100-39-0 benzyl bromide 
• 123-09-1 4-chlorophenyl methyl sulfide 

Relevant academic research and scientific papers

Reductive Difunctionalization of Aryl Alkenes with Sodium Metal and Reduction-Resistant Alkoxy-Substituted Electrophiles

A general method for alkali-metal-promoted reductive difunctionalization of alkenes has been developed by means of reduction-resistant alkoxy-substituted electrophiles. A series of 1,2-diboration and 1,2-dicarbofunctionalization products can be synthesize

Promotion of the photoacid generation performance of sulfonium salts by inhibiting the isomerization of conjugated systems using a cyclization strategy

This work describes an original structure?reactivity relationship within a series of sulfonium salts synthesized using a cyclization strategy. The new sulfonium salt comprises a stilbene subunit decorated with a combination of cyclized structure, that is, carbocyclic ring, furan ring, and thiophene ring, to inhibit the isomerization of double bond systems. The photoacid generation efficiency of such cyclized stilbene derivative sulfonium salts is mainly modulated by the five-membered ring structures and the substituent as confirmed by photodegradation, in situ nuclear magnetic resonance, and cyclic voltammetry. Such cyclization drastically regulates the population of highly reactive excited singlet species and thus enhances the photoacid generation performance of the sulfonium salts by more than one order of magnitude within the series, especially when introducing oxygen to form the benzofuran ring structure. Given this amplified photoreactivity, the application potential of the photoinitiated cationic polymerization of the sulfonium salts was evaluated at different irradiation wavelengths.

Sulfonium compound containing acyl phosphine oxide and diphenyl ethylene, and preparation method and application of compound

The invention provides a sulfonium compound containing acyl phosphine oxide and diphenyl ethylene, and a preparation method and an application of the sulfonium compound. In the sulfonium compound, R0is selected from hydrogen, a halogen atom, R, OR, SOR, S

Novel diaryl sulfonium salt compound containing diphenylethene groups as well as preparation method and application thereof

The invention relates to the technical field of new material organic chemicals, and particularly relates to a novel diaryl sulfonium salt shown as a formula (I) and having a diphenylethene conjugatedstructure, a chemical process preparation technique ther

Microwave assisted catalytic activity of some bis-5(6)-nitrobenzimidazole salts for Heck and Suzuki cross-coupling reactions

A mixture of bis-5(6)-nitrobenzimidazole salts (2a-h), Pd(OAc)2 and K2CO3 in DMF-H2O catalyzes, in good yield the Suzuki and Heck cross-coupling reactions for synthesis of biaryl and stilbene derivatives assisted by microwave irradiation in the short time.

Synthesis and microwave-assisted catalytic activity of novel bis-benzimidazole salts bearing furfuryl and thenylmoieties in heck and suzuki cross-coupling reactions

A mixture of bis-benzimidazole salts (1-7), Pd(OAc)2 and K 2CO3 in DMF - H2O catalyzes, in high yield, the Suzuki and Heck cross-coupling reactions assisted by microwave irradiation in a short time. In particular, the yields of the Heck and Suzuki reactionswith aryl bromideswere found to be nearly quantative. The synthesized bis-benzimidazole salts (1-7) were identified by 1H-13C NMR, IR spectroscopic methods and micro analysis. Copyright