454479-46-0

Upstream product

• 100-39-0 benzyl bromide 
• 20585-18-6 methyl 4,6-dideoxy-α-D-glucopyranoside 
• 4990-91-4 (2S,3R,4R,5S,6R)-5-chloro-6-(chloromethyl)-2-methoxytetrahydro-2H-pyran-3,4-diol 
• 97-30-3 methyl-alpha-D-glucopyranoside 
• 454479-44-8 methyl 2-O-acetyl-4,6-dideoxy-α-D-glucopyranoside 
• 454479-45-9 Acetic acid (2S,3R,4S,6R)-2-methoxy-4-methoxymethoxy-6-methyl-tetrahydro-pyran-3-yl ester 
• 454479-43-7 Acetic acid (2S,3R,4S,6R)-4-benzyloxy-2-methoxy-6-methyl-tetrahydro-pyran-3-yl ester 

Downstream Products

• 72212-12-5 (2S,3S,6R)-3-Benzyloxy-2-methoxy-6-methyl-tetrahydro-pyran-4-one 
• 294178-42-0 (2S,3R,4R,6R)-3-Benzyloxy-2-methoxy-6-methyl-tetrahydro-pyran-4-ol 
• 294178-43-1 (2S,3R,4S,6R)-4-Azido-3-benzyloxy-2-methoxy-6-methyl-tetrahydro-pyran 
• 294178-45-3 Phosphoric acid (2R,3R,4S,6R)-4-azido-3-benzyloxy-6-methyl-tetrahydro-pyran-2-yl ester dibenzyl ester 
• 451505-76-3 (2S,3R,4S,6R)-3-Benzyloxy-2-methoxy-6-methyl-tetrahydro-pyran-4-ol 

Relevant academic research and scientific papers

Synthesis of TDP-3-amino-3,4,6-trideoxy-α-D-xylo-hexopyranose - The immediate precursor of TDP-α-D-desosamine

A synthetic pathway producing the title compound starting from methyl α-D-glucose is described. This compound was shown to be a substrate for DesVI, an AdoMet-dependent methyltransferase which catalyzes N,N-dimethylation of the title compound to give a biological significant unusual sugar, desosamine.