4560-54-7Relevant articles and documents
The Reaction of Dimethyldioxirane with Alkynes
Murray, Robert W.,Singh, Megh
, p. 5076 - 5080 (1993)
The reaction of dimethyldioxirane with several alkynes gives products which are conveniently rationalized by postulating the intermediacy of oxirenes and oxocarbenes.The latter serve as precursors to H atom or methyl group migration products, as well as to cyclopropane insertion products in some cases.Alkenes, derived from some of these carbene reactions, are partially converted to epoxides.