Journal of Organic Chemistry p. 5076 - 5080 (1993)
Update date:2022-08-02
Topics:
Murray, Robert W.
Singh, Megh
The reaction of dimethyldioxirane with several alkynes gives products which are conveniently rationalized by postulating the intermediacy of oxirenes and oxocarbenes.The latter serve as precursors to H atom or methyl group migration products, as well as to cyclopropane insertion products in some cases.Alkenes, derived from some of these carbene reactions, are partially converted to epoxides.
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