457959-68-1Relevant academic research and scientific papers
Cheap and efficient preparation method of benzene triimide and derivative thereof
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Paragraph 0066; 0074-0079, (2020/05/01)
The invention discloses a preparation method of benzene triimide (BTI) and a derivative thereof, wherein the structural general formula of the compound is represented by a formula I. The preparation method comprises the following steps: under the condition of refluxing in a mixed solution of acetic acid and water, carrying out an intermolecular aromatic ring construction reaction on a maleimide derivative represented by a formula II to obtain the benzene triimide (BTI) and the derivative I thereof. According to the invention, the cheap and easily available raw materials maleic anhydride and maleimide and the cheap and easily available primary amine compound are selected and subjected to simple addition, elimination and amination to rapidly prepare a large amount of maleimide derivatives, and further the maleimide derivatives are subjected to an intermolecular cyclization reaction to rapidly prepare the benzene triimide (BTI) and the derivative thereof in one step, so that the reactionconditions are mild, and the obtained product is stable in air and easy to separate and purify, and has good application prospect.
One-pot synthesis and structure∑property relationship of aminomaleimides: Fluorescence efficiencies in monomers and aggregates easily tuned by switch of aryl and alkyl
Zhu, Qiuhua,Ye, Ziwei,Yang, Weijie,Cai, Xiaotie,Tang, Ben Zhong
, p. 1096 - 1104 (2018/05/14)
Organic fluorophores have attracted great interest owing to their wide applications. They usually contain an electron-conjugated system with an aromatic moiety and show high emission in dilute solutions but weaker or even no emission upon aggregation. Her
Lewis acid-promoted cascade reaction of primary amine, 2-butynedioate, and propargylic alcohol: A convenient approach to 1,2-dihydropyridines and 1H-pyrrolo[3,4-b]pyridine-5,7(2H,6H)-diones
Yin, Guangwei,Zhu, Yuanxun,Wang, Ningning,Lu, Ping,Wang, Yanguang
, p. 8353 - 8359 (2013/09/02)
1,2-Dihydropyridine-5,6-dicarboxylates were efficiently constructed through a cascade reaction of primary amine, 2-butynedioate and propargylic alcohol in the presence of Lewis acid under mild conditions. As exceptional, 1H-pyrrolo[3,4-b]pyridine-5,7(2H,6
