459132-89-9Relevant articles and documents
Stereoselective preparation of (E)- and (Z)-α-fluorostilbenes via palladium-catalyzed cross-coupling reaction of high E/Z ratio and (Z)-1-bromo-1-fluoroalkenes
Xu, Jianjun,Burton, Donald J.
, p. 3743 - 3747 (2007/10/03)
A highly stereoselective method to prepare both (E)- and (Z)-α-fluorostilbenes is described. 1-Bromo-1-fluoroalkenes (E/Z ≈ 1:1), a readily available starting material, isomerizes to high E/Z ratios by storage at -20 °C or by photolysis at 254 nm. Stille