459132-91-3Relevant academic research and scientific papers
A simple, two-step, site-specific preparation of fluorinated naphthalene and phenanthrene derivatives from fluorobromo-substituted alkenes
Wang, Yi,Xu, Jianjun,Burton, Donald J.
, p. 7780 - 7784 (2006)
(Chemical Equation Presented) A facile two-step procedure for the site-specific preparation of fluorinated naphthalene and phenanthrene derivatives is described. The Sonogashira reaction of bromofluoro-substituted alkenes with terminal alkynes, followed b
Reactions of carbonyl compounds with phosphorus ylide generated from tribromofluoromethane and tris(dimethylamino)phosphine
Hirai, Go,Nishizawa, Eri,Kakumoto, Daiki,Morita, Masaki,Okada, Mitsuaki,Hashizume, Daisuke,Nagashima, Sayoko,Sodeoka, Mikiko
supporting information, p. 1389 - 1391 (2015/11/17)
The reactions of fluorinated ylide, generated from tris(dimethylamino) phosphine and tribromofluoromethane, with simple aldehydes and reactive ketones gave the expected Wittig reaction products. However, a ketone having a galactose skeleton afforded an acid fluoride, probably through an unprecedented CoreyChaykovski- type epoxide formation reaction, followed by spontaneous Meinwald rearrangement.
A facile and mild method for the synthesis of terminal bromofluoroolefins via diethylzinc-promoted wittig reaction
Lei, Xinsheng,Dutheuil, Guillaume,Pannecoucke, Xavier,Quirion, Jean-Charles
, p. 2101 - 2104 (2007/10/03)
Synthesis of 1-bromo-1-fluoroolefins was achieved in good yields via a Wittig reaction promoted by diethylzinc, even with nonactivated aldehydes and ketones as starting materials.
Stereospecific preparation of (Z)-α-fluorostilbenes via a kinetically controlled palladium-catalyzed cross-coupling reaction of high E/Z ratio 1-bromo-1-fluorostyrenes and aryl stannanes
Xu, Jianjun,Burton, Donald J
, p. 2877 - 2879 (2007/10/03)
High E/Z ratios were obtained for 1-bromo-1-fluorostyrenes by isomerization from the original E/Z ratios of approximately 1:1. The palladium-catalyzed cross-coupling reaction of high E/Z ratio 1-bromo-1-fluorostyrenes with aryl stannanes gives (Z)-α-fluor
