4595-23-7Relevant academic research and scientific papers
Cell-surface engineering by a conjugation-and-release approach based on the formation and cleavage of oxime linkages upon mild electrochemical oxidation and reduction
Pulsipher, Abigail,Dutta, Debjit,Luo, Wei,Yousaf, Muhammad N.
supporting information, p. 9487 - 9492 (2015/01/06)
We report a strategy to rewire cell surfaces for the dynamic control of ligand composition on cell membranes and the modulation of cell-cell interactions to generate three-dimensional (3D) tissue structures applied to stem-cell differentiation, cell-surfa
A Convenient Synthesis of 2-Alkylated 1,4-Benzenediols
Ozaki, Yutaka,Hosoya, Ayako,Okamura, Kyouko,Kim, Sang-Won
, p. 365 - 366 (2007/10/03)
Reaction of 1,4-cyclohexanedione with a variety of aldehydes in the presence of metal halides generated the 2-alkylated 1,4-benzenediols in good yields without any aromatic by-products.
Hydrophobic acceleration of electron transfer processes
Shi, Ji-Liang,Chen, Xin,Jiang, Xi-Kui
, p. 4698 - 4702 (2007/10/03)
Electron transfer processes between 1-α-naphthyl-3-oxa-alkanes (1-n, n = 1, 8, 12, 16) and 2-alkyl-3,5,6-trichloro-1,4-benzoquinones (2-n, n = 8, 12, 16) facilitated by hydrophobic-lipophilic interactions (HLI) have been investigated by means of fluorescence spectroscopy in dioxane-H2O systems of different ψ values, where ψ is the volume fraction of the organic component of an aquiorgano mixture. Three lines of evidence, namely, EPR, UV-vis, and fluorescence quenching, indicate that electron transfer between 1-12 and 2-12 has occurred. Furthermore, both UV-vis evidence and the near constancy of the life time τ of 1-12* in the presence of different concentrations of the quencher 2-12 show that the electron transfer is preceded by preassociation, i.e., the quenching process is static. Therefore, the extent of HLI-driven coaggregation (preassociation) between the donors and the acceptors may be assessed from the Stern-Volmer slopes (Ksv). The chain-length effect, and possibly also a chain-foldability effect, has been observed. A notable observation is the importance of solvent aggregating power (SAgP) effect, which is indicated by the surge of Ksv values at ψ ≤ 0.40 (dioxane-H2O) for monomeric 1-12.
