460-70-8Relevant articles and documents
Preparation process of 1, 1-dichloro-3, 3, 3-trifluoropropene
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Paragraph 0050; 0074-0092, (2020/11/01)
The invention relates to a method for producing a 1, 1-dichloro-3, 3, 3-trifluoropropene with high added value by taking trifluoromethane and trichloroethylene as raw materials. According to the method, a catalytic system composed of a main catalyst and a catalytic auxiliary agent of specific types in a special proportion is adopted; wherein the active component of the main catalyst is selected from one or more of Fe, Co, Ni, Ru, Rh, Pd, Pt, Cu, Ag and Au, multi-stage micro/mesoporous Cr2O3 is adopted as a carrier, and a metal oxide and/or a rare earth auxiliary agent is adopted as a catalyticauxiliary agent, so that the selectivity on the target product 1, 1-dichloro-3, 3, 3-trifluoropropene is effectively improved. According to the method disclosed by the invention, not only the resource utilization of the byproduct trifluoromethane is promoted, but also the types of raw materials of the 1, 1-dichloro-3, 3, 3-trifluoropropene product are expanded, and remarkable economic benefits and social benefits are generated.
PROCESS FOR 1-CHLORO-3,3,3-TRIFLUOROPROPENE FROM TRIFLUOROMETHANE
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Paragraph 0061; 0063, (2015/02/25)
The present invention provides routes for making 1-chloro-3,3,3-trifluoropropene (HCFO-1233zd) from commercially available raw materials. More specifically, this invention provides routes for HCFO-1233zd from inexpensive and commercially available trifluoromethane (HFC-23).