7125-84-0Relevant academic research and scientific papers
Method for preparing 3,3,3-trichloro-1,1,1-trifluoropropane through gas-phase catalytic chlorination
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Paragraph 0032-0043, (2021/06/22)
The invention discloses a method for preparing 3,3,3-trichloro-1,1,1-trifluoropropane through gas-phase catalytic chlorination through gas-phase catalytic chlorination. The method comprises the following step: under the action of a catalyst, subjecting 3,3-dichloro-1,1,1-trifluoropropane and chlorine serving as raw materials to a gas-phase catalytic chlorination reaction in a catalyst bed layer, wherein the catalyst is a molecular sieve, and the molecular sieve is at least one selected from ZSM-5, 5A, MCM-41, a beta type molecular sieve and a Y type molecular sieve. The molecular sieve which is cheap and easy to obtain is used as the catalyst, the reaction is carried out under a gas phase condition, and the method has the advantages of high space time yield, simple process, safe operation, low production cost and the like.
MANUFACTURING METHOD OF 1,1,1-TRICHLORO-3,3,3-TRIFLUOROPROPANE
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Paragraph 0011; 0046-0048; 0054, (2017/03/28)
PROBLEM TO BE SOLVED: To provide an efficient manufacturing method of 1,1,1-trichloro-3,3,3-trifluoropropane (HCFC-233fb) with high safety. SOLUTION: There is provided a manufacturing method of HCFC-233fb by contacting trichlorofluoromethane and 1,1-difluoroethylene in a presence of a catalyst. Preferably there is provided a manufacturing method of HCFC-233fb where the catalyst is a Lewis acid catalyst. More preferably there is provided a manufacturing method of HCFC-233fb where the Lewis acid catalyst is halide or halogenated oxide of at least one element selected from B, Al, Ga, In, Fe, Ni, Co, Sb, Nb, Sn, Ti, Zr, Hf, W and Ta. SELECTED DRAWING: None COPYRIGHT: (C)2016,JPOandINPIT
PROCESS FOR 1-CHLORO-3,3,3-TRIFLUOROPROPENE FROM TRIFLUOROPROPENE
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Paragraph 0073, (2015/02/25)
The present invention provides routes for making 1-chloro-3,3,3-trifluoropropene (HCFO-1233zd) from commercially available raw materials. More specifically, this invention provides several routes for forming HCFO-1233zd from 3,3,3-trifluoropropene (FC-1234zf).
