46030-10-8Relevant academic research and scientific papers
Synthesis and characterization of gallium(III) dithiocarbamates as suitable nano-gallium(III) sulfide precursors
Ramalingam, Kuppukkannu,Sivagurunathan,Rizzoli, Corrado
, p. 75 - 82 (2015)
Gallium(III) complexes [Ga(chmdtc)3] (1) and [Ga(chedtc)3] (2) (where chmdtc=cyclohexylmethyldithiocarbamate and chedtc=cyclohexylethyldithiocarbamate) have been prepared and characterized by infrared, nuclear magnetic resonance (1H and 13C) spectra, thermogravimetry, X-ray photoelectron spectroscopy, and single crystal X-ray diffraction (XRD). The thermogravimetric curves obtained for both complexes are almost similar. The final residue corresponded to gallium sulfide (Ga2S3) above 700°C for complexes (1) and (2). In the single crystal X-ray structure of [Ga(chedtc)3] (2), Ga-S bonds, and the associated C-S bonds show asymmetry as a requirement of packing. The complex shows distorted octahedral geometry due to its bite angle variations. Nano-α-Ga2S3 was prepared from single source precursors [Ga(chmdtc)3] (1) and [Ga(chedtc)3] (2). Prepared nano-Ga2S3 have been characterized by powder XRD, energy-dispersive X-ray spectroscopy technique, and transmission electron microscopy (TEM)-selected area electron diffraction analysis showing the nano-sized nature of Ga2S3. TEM micrographs confirmed the size of the particles to be 50 nm.
Metal dithiocarbamate precursors for the preparation of a binary sulfide and a pyrochlore: Synthesis, structure, continuous shape measure and bond valence sum analysis of antimony(III) dithiocarbamates
Sivasekar, Subburayan,Ramalingam, Kuppukkannu,Rizzoli, Corrado
, p. 598 - 606 (2015/02/19)
The antimony(III) complexes [Sb(chmdtc)3] (1), [Sb(chedtc)3] (2) and [Sb(dchdtc)3] 0.5 C7H8 (3) (where chmdtc = cyclohexylmethyldithiocarbamate, chedtc = cyclohexylethyldithiocarbamate and dchdtc = di
Continuous Shape Measure of electronic effect free steric distortions in tris(dithiocarbamato)indium(III): Synthesis, spectral, electrochemical, single crystal X-ray structural investigations and BVS calculations on tris(dithiocarbamato)indium(III) comple
Sivagurunathan, Gurunathan Senthilkumar,Ramalingam, Kuppukkannu,Rizzoli, Corrado
, p. 96 - 102 (2014/03/21)
Geometrical distortions from an ideal octahedral geometry (iOh) towards an ideal trigonal prism (itp) in tris(dithiocarbamato)indium(III) complexes have been quantified by Continuous Shape Measure (CShM) analysis. Three tris(disubstituted dithiocarbamato)
Synthesis, structural, Continuous Shape Measure and bond valence sum characterization of bismuth(III) complexes of substituted dithiocarbamates and their solvothermal decomposition
Sivasekar, Subburayan,Ramalingam, Kuppukkannu,Rizzoli, Corrado,Alexander, Nagarajan
, p. 82 - 88 (2014/06/23)
Bismuth(III) complexes, [Bi(chmdtc)3] (1) [Bi(chedtc) 3] (2) and [Bi(dchdtc)3] (3) (where chmdtc = cyclohexylmethyldithiocarbamate, chedtc = cyclohexylethyldithiocarbamate and dchdtc = dicyclohexyldithiocarbamate) have bee
Nanothallium(III) sulfide from dithiocarbamate precursors: Synthesis, single crystal X-ray structures and characterization
Sivagurunathan,Ramalingam,Rizzoli
, p. 316 - 321 (2013/10/08)
Nanothallium sulfide was formed from Tl(chmdtc)3(1), Tl(chedtc)3(2) and Tl(dchdtc)3(3) (where chmdtc = cyclohexyl methyl dithiocarbamate, chedtc = cyclohexylethyl dithiocarbamate, dchdtc = dicyclohexyl dithiocarbamate). Si
Supramolecularly linked linear polymers of thallium(I) dithiocarbamates: Steric influence on the supramolecular interactions of methyl and ethylcyclohexyl dithiocarbamates of thallium(I)
Alexander, Nagarajan,Ramalingam, Kuppukkannu,Rizzoli, Corrado
experimental part, p. 480 - 483 (2011/03/20)
Spectral and single crystal X-ray structural studies on [Tl(mchdtc)] 2 (1) and [Tl(echdtc)]2 (2) (where mchdtc = methylcyclohexyldithiocarbamate and echdtc = ethylcyclohexyldithiocarbamate) were carried out. Both the synthesized comp
