460752-11-8

Basic information

• Product Name: 1-phenyl-1-(2-tetrahydropyranyloxy)-3-butyne
• Synonyms: 1-phenyl-1-(2-tetrahydropyranyloxy)-3-butyne
• CAS NO: 460752-11-8
• Molecular Weight: 230.307
• Mol File: 460752-11-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1-phenyl-1-(2-tetrahydropyranyloxy)-3-butyne(CAS DataBase Reference)
• NIST Chemistry Reference: 1-phenyl-1-(2-tetrahydropyranyloxy)-3-butyne(460752-11-8)
• EPA Substance Registry System: 1-phenyl-1-(2-tetrahydropyranyloxy)-3-butyne(460752-11-8)

Safety Data

• Hazardous Substances Data: 460752-11-8(Hazardous Substances Data)

Upstream product

• 3174-74-1 dihydropyran 
• 1743-36-8 1-phenylbut-3-yn-1-ol 
• 100-52-7 benzaldehyde 
• 110-87-2 3,4-dihydro-2H-pyran 

Downstream Products

• 4660-19-9 5-hydroxy-5-phenyl-pent-2-ynoic acid methyl ester 
• 35390-18-2 1-phenyl-3-hexyn-1-ol 
• 1274824-03-1 3-[2-phenyl(tetrahydro-2H-pyran-2-yloxy)ethyl]pyrano-[3',4':4,5]imidazo[1,2-a]pyridin-1-one 
• 460752-86-7 (Z)-4-benzyldimethylsilyl-1-phenyl-3-octen-1-ol 
• 460752-85-6 (Z)-4-dimethylphenylsilyl-1-phenyl-3-octen-1-ol 
• 460752-52-7 (E)-4-benzyldimethylsilyl-4-bromo-1-phenyl-1-(2-tetrahydropyranyloxy)-3-butene 
• 460752-51-6 (E)-4-bromo-4-dimethylphenylsilyl-1-phenyl-1-(2-tetrahydropyranyloxy)-3-butene 
• 460752-20-9 4-dimethylphenylsilyl-1-phenyl-1-(2-tetrahydropyranyloxy)-3-butyne 
• 460752-21-0 4-benzyldimethylsilyl-1-phenyl-1-(2-tetrahydropyranyloxy)-3-butyne 

Relevant articles and documents

Acyloxy Rearrangement-Triggered Regioselective Hydration of ?-Acetoxy-α,β-Alkynoates/Halo Alkynes

Herein, we report a simple, efficient, highly regioselective, and broad-scope hydration method that is facilitated by an unusual interception of an electrophilic intermediate by water generated via acetate group participation during [3,3]-acyloxy rearrang

Ruthenium-catalyzed [2 + 2] cycloadditions between norbornene and propargylic alcohols or their derivatives

Diastereoselective ruthenium-catalyzed [2 + 2] cycloadditions of norbornene and propargylic alcohols or their derivatives were investigated. The cycloadditions were found to be highly stereoselective, giving exo cycloadducts in moderate to excellent yields with diastereoselectivities up to 92:8. When a chiral propargylic alcohol was used in the cycloaddition, up to 80% ee of the [2 + 2] cycloadducts was observed after oxidation of the alcohol.