4660-19-9Relevant academic research and scientific papers
Mixed crossed aldol condensation between conjugated esters and aldehydes using aluminum tris(2,6-diphenylphenoxide)
Saito, Susumu,Shiozawa, Masahito,Yamamoto, Hisashi
, p. 1769 - 1771 (1999)
The combined use of aluminum tris(2,6-diphenylphenoxide) (ATPH) and lithium 2,2,6,6-tetramethylpiperidide (LTMP) has proven to be effective for the mixed crossed aldol condensation between conjugated esters and various aldehydes. An example is shown in Eq
Acyloxy Rearrangement-Triggered Regioselective Hydration of ?-Acetoxy-α,β-Alkynoates/Halo Alkynes
Mendhekar, Kishor L.,Mohapatra, Debendra K.,Pradhan, Tapas R.
, p. 4881 - 4895 (2020/05/01)
Herein, we report a simple, efficient, highly regioselective, and broad-scope hydration method that is facilitated by an unusual interception of an electrophilic intermediate by water generated via acetate group participation during [3,3]-acyloxy rearrang
