46115-40-6

Upstream product

• 60556-85-6 2-Fluoroprop-2-enoyl fluoride 
• 108-95-2 phenol 
• 102093-99-2 ethyl phenyl bromoacetal 
• 102069-99-8 1-ethoxy-1-phenoxy ethylene 
• 154918-01-1 3,3-dichloro-2-fluoroacrylate de phenyle 
• 16522-55-7 α-fluoroacryloyl chloride 
• 96625-72-8 Phenyl 2,3-dibromo-2-fluoropropanoate 
• 75-43-4 Dichlorofluoromethane 

Relevant academic research and scientific papers

Access to 2-fluoroacrylates and their 3-chloro derivatives by chemical hydrogenolysis of 3,3-dichloro-2-fluoroacrylates

The formation of 3-chloro-2-fluoroacrylates 2 and 2-fluoroacrylates 3 by hydrogenolysis of 3,3-dichloro-2-fluoroacrylates 1 was studied by using Bu3SnH, zinc, the sodium sulphite/sodium formate mixture or iron pentacarbonyl in the presence of a

REACTION OF HALOGEN FLUORIDES. IX. SYNTHESIS OF DERIVATIVES OF α-FLUOROACRYLIC ACID

New methods have been proposed for the preparation of derivatives of α-fluoroacrylic acid by the substituent fluorination of 1,2-dibromo-3-chloropropane and methyl 2,3-dibromo-2-chloropropanoate with bromine trifluoride.

THERMOLYSIS OF THE CHLOROFLUOROCARBENE 1-ETHOXY-1-PHENOXYETHYLENE ADDUCT TO PHENYL 2-FLUOROACRYLATE

The preparation of 1-ethoxy-1-phenoxyethylene 1 is described.Its condensation with chlorofluorocarbene gives 2,2-chlorofluorocyclopropanone acetal 2, thermolysis of which leads to phenyl 2-fluoroacrylate 3.

Photochemical Bromination of 2-Fluoroacrolein: Synthesis of Phenyl 2-Fluoroacrylate

Phenyl 2-fluoroacrylate (1) is prepared by debromination of the dibromo compound 7, obtained in turn by the photobromination of 2-fluoroacrolein (2) followed by treatment with phenol.

Process for making an acrylic monomer

The invention relates to a novel process for making phenyl fluoroacrylate monomer. The monomer is obtained by reaction of a fluoroacrylic salt with an halogenating agent, followed by condensation of the fluoroacryloyl halogenide with phenol and recovery of the phenyl fluoroacrylate. The obtained monomer is applicable to the manufacture of transparent polymers of high thermal stability.