463927-80-2Relevant academic research and scientific papers
Studies in bicyclo[3.1.0]hexane methanolysis. Ring opening of activated cyclopropanes under acidic and basic conditions
Lim, Yeon-Hee,McGee Jr., Kevin F.,Sieburth, Scott McN.
, p. 6535 - 6538 (2002)
A bicyclo[3.1.0]hexane, with one cyclopropane carbon flanked by a ketone and an ester or an aldehyde, undergoes methanolysis with cleavage of one of the two activated cyclopropane bonds, depending on the reaction conditions. Acidic conditions yield primarily or exclusively a 4-methoxycyclohexane, while basic conditions yield a 3-methoxymethylcyclopentanone.
Carbanion stabilization by distal silyloxy groups. Origin of the high diastereoselectivity in the formation of quaternary centers with aryllead(IV) triacetate reagents
Konopelski, Joseph P.,Lin, Jinzhen,Wenzel, Philip J.,Deng, Hongbo,Elliott, Gregory I.,Gerstenberger, Brian S.
, p. 4121 - 4123 (2007/10/03)
(formula presented) Derivatives of methyl 5-hydroxy-2-oxo-1-cyclohexanecarboxylate react with aryllead(IV) reagents in high yield and with wide variation in diastereoselectivity. Ab initio calculations are consistent with a heretofore unrecognized attract
