4680-20-0Relevant articles and documents
Aluminum phenoxide-promoted alkylation of phenol with α- And β-pinenes
Kutchin,Shumova,Chukicheva, I. Yu.
, p. 450 - 453 (2014/01/17)
Alkylation of phenol with natural α- and β-pinenes in the presence of Al(OPh)3 gives the O- and C-alkylation products with the structurally different terpene fragments. The terpenophenols obtained have proved to be optically active.
Tandem molecular rearrangement in the alkylation of phenol with camphene
Chukicheva,Spirikhin,Kuchin
, p. 62 - 66 (2008/12/21)
The alkylation of phenol with camphene in the presence of boron trifluoride in glacial acetic acid was accompanied by tandem molecular rearrangement with formation of a mixture of ortho- and para-substituted phenols having 1,7,7-trimethylbicyclo[2.2.1]hept-exo-2-yl and 5,5,6-trimethylbicyclo[2.2.1] hept-exo-2-yl substituents. The same products were obtained by rearrangement of 1,7,7-trimethylbicyclo[2.2.1]hept-exo-2-yloxybenzene under analogous conditions. Similar reactions performed in the presence of aluminum phenoxide as catalyst resulted in predominant formation of the corresponding ortho-substituted phenols.