469898-64-4

Upstream product

• 917-64-6 methyl magnesium iodide 
• 188255-39-2 3-isopropoxy-4-methoxy-2-(prop-2'-enyl)benzaldehyde 
• 18075-40-6 O-allylisovanillin 
• 18075-41-7 2-allyl-3-hydroxy-4-methoxybenzaldehyde 
• 75-16-1 methylmagnesium bromide 

Downstream Products

• 469898-44-0 (R)-3-isopropoxy-4-methoxy-1-(1'-hydroxyethyl)-2-(prop-1''-enyl)benzene 
• 469898-56-4 1-[3-Isopropoxy-4-methoxy-2-((E)-propenyl)-phenyl]-ethanone 
• 469898-41-7 1-(2-allyl-3-isopropoxy-4-methoxy-phenyl)-ethanone 

Relevant academic research and scientific papers

Towards the synthesis of chiral isochromanquinones. The use of Corey-Bakshi-Shibata reductions

(1R,3R,4S)-3,4-Dihydro-4-hydroxy-6-methoxy-1,3-dimethylisochroman-5,8-dione has been synthesized in 65% ee from (1R,3R,4S)-5-benzyloxy-3,4-dihydro-4-hydroxy-6-methoxy-1,3-dimethylisochroman by catalytic hydrogenolysis followed by Fremy's salt oxidation of

The synthesis of R-3-alkoxy-1-(1′-hydroxyethyl)-4-methoxy-2-(1″-propenyl)benzenes utilizing Corey-Bakshi-Shibata asymmetric reductions

Pyrolysis of the 3-O-allyl derivative 7 of isovanillin followed by alkylation of the derived allylphenol 8 afforded a series of benzaldehyde derivatives 9-11 each of which was transformed by initial treatment with methylmagnesium bromide followed by oxida