471269-99-5

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 470690-19-8 (1R,2S,4S)-1-hydroxymethyl-3,3-dimethyl-7-oxabicyclo[2.2.1]hept-5-ene-2-carboxylic acid ethyl ester 
• 301823-96-1 (1R,2S,4S)-3,3-dimethyl-1-[(2R*)-tetrahydropyran-2-yloxymethyl]-7-oxabicyclo[2.2.1]hept-5-ene-2-carboxylic acid ethyl ester 
• 471269-86-0 (1R,2S,4R,5S)-5-hydroxy-3,3-dimethyl-1-[(2R*)-tetrahydropyran-2-yloxymethyl]-7-oxabicyclo[2.2.1]heptane-2-carboxylic acid ethyl ester 
• 471269-89-3 (+)-(1R,2S,4R,5S)-[5-(tert-butyldiphenylsilyloxy)-3,3-dimethyl-2-vinyl-7-oxabicyclo[2.2.1]heptan-1-yl]methanol 
• 471269-88-2 (1R,2S,4R,5S)-5-(tert-butyldiphenylsilyloxy)-3,3-dimethyl-1-[(2R*)-tetrahydropyran-2-yloxymethyl]-7-oxabicyclo[2.2.1]heptane-2-carbaldehyde 
• 471269-82-6 (1R,2S,4R,5S)-tert-butyl{6,6-dimethyl-4-[(2R*)-tetrahydropyran-2-yloxymethyl]-5-vinyl-7-oxabicyclo[2.2.1]heptan-2-yloxy}diphenylsilane 
• 471269-87-1 (1R,2S,4R,5S)-5-{(tert-butyldiphenylsilyloxy)-3,3-dimethyl-1-[(2R*)-tetrahydropyran-2-yloxymethyl]-7-oxabicyclo[2.2.1]heptane-2-yl}methanol 
• 301823-97-2 (1R,2S,4R,5S)-5-(tert-butyldiphenylsilyloxy)-3,3-dimethyl-1-[(2R*)-tetrahydropyran-2-yloxymethyl]-7-oxabicyclo[2.2.1]heptane-2-carboxylic acid ethyl ester 
• 471269-92-8 rac-5-[3-(tert-butyldiphenylsilyloxy)propyl]=2-hydroxycyclohex-1-enecarboxylic acid methyl ester 
• 471269-91-7 4-[3-(tert-butyldiphenylsilyloxy)propyl]cyclohexanone 
• 5597-54-6 4-(3-hydroxypropyl)cyclohexanone 
• 301823-94-9 (+)-(1R,2S,4R,5S)-5-(tert-butyldiphenylsilyloxy)-3,3-dimethyl-2-vinyl-7-oxabicyclo[2.2.1]heptancarboxaldehyde 
• 471269-84-8 rac-5-[3-(tert-butyldiphenylsilyloxy)propyl]-2-trifluoromethylsulfonyloxycyclohex-1-enecarboxylic acid methyl ester 

Downstream Products

• 471270-05-0 (S)-[(1R,2S,4R,5S)-5-(tert-Butyl-diphenyl-silanyloxy)-3,3-dimethyl-2-vinyl-7-oxa-bicyclo[2.2.1]hept-1-yl]-{4-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-2-hydroxymethyl-cyclohex-1-enyl}-methanol 
• 471270-12-9 C₅₄H₆₈O₅Si₂ 
• 471270-10-7 Acetic acid (S)-[(1R,2S,4R,5S)-5-(tert-butyl-diphenyl-silanyloxy)-3,3-dimethyl-2-vinyl-7-oxa-bicyclo[2.2.1]hept-1-yl]-{4-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-2-formyl-cyclohex-1-enyl}-methyl ester 
• 471270-11-8 Acetic acid (S)-[(1R,2S,4R,5S)-5-(tert-butyl-diphenyl-silanyloxy)-3,3-dimethyl-2-vinyl-7-oxa-bicyclo[2.2.1]hept-1-yl]-{4-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-2-vinyl-cyclohex-1-enyl}-methyl ester 
• 471270-08-3 Acetic acid (S)-[(1R,2S,4R,5S)-5-(tert-butyl-diphenyl-silanyloxy)-3,3-dimethyl-2-vinyl-7-oxa-bicyclo[2.2.1]hept-1-yl]-{4-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-2-hydroxymethyl-cyclohex-1-enyl}-methyl ester 
• 471270-18-5 C₅₅H₆₈O₇Si₂ 
• 471270-16-3 C₅₄H₆₈O₇Si₂ 
• 1053635-24-7 C₅₄H₆₆O₇Si₂ 
• 471270-06-1 {2-(tert-butyl-dimethyl-silanyloxymethyl)-4-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-cyclohex-1-enyl}-[5-(tert-butyl-diphenyl-silanyloxy)-3,3-dimethyl-2-vinyl-7-oxa-bicyclo[2.2.1]hept-1-yl]-methanol 
• 471270-07-2 acetic acid {2-(tert-butyl-dimethyl-silanyloxymethyl)-4-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-cyclohex-1-enyl}-[5-(tert-butyl-diphenyl-silanyloxy)-3,3-dimethyl-2-vinyl-7-oxa-bicyclo[2.2.1]hept-1-yl]-methyl ester 

Relevant academic research and scientific papers

Studies towards the total synthesis of solanoeclepin A: Synthesis and potato cyst nematode hatching activity of analogues containing the tetracyclic left-hand substructure

In our studies towards the total synthesis of solanoeclepin A, a natural hatching agent of potato cyst nematodes, three analogues containing the tetracyclic left-handed substructure have been synthesised. First, the synthesis of the parent tetracycle 2 in