474116-08-0Relevant academic research and scientific papers
Regio- and diastereoselective functionalization of (-)-cytisine: An unusual N-C acyl migration
Rouden, Jacques,Ragot, Alexis,Gouault, Sonia,Cahard, Dominique,Plaquevent, Jean-Christophe,Lasne, Marie-Claire
, p. 1299 - 1305 (2007/10/03)
In order to test (-)-cytisine as a potential chiral inductor, N-propionyl cytisine was treated with LDA and then with benzyl bromide. Instead of the expected α-benzyl substituted propionamide, (-)-N-benzyl 6α-propionyl cytisine was formed, arising from an
