474958-72-0

Upstream product

• 475987-09-8 (+)-B-γ-methoxyethoxymethoxyallyldiisopinocampheylborane 
• 100-52-7 benzaldehyde 
• 474958-70-8 (1S,2S)-2-(2-methoxy-ethoxymethoxy)-1-phenyl-but-3-en-1-ol 
• 77120-79-7 1-<(2-methoxyethoxy)methoxy>-2-propene 
• 618439-33-1 (2S)-2-(2-methoxy-ethoxymethoxy)-1-phenyl-but-3-en-1-one 
• 474958-71-9 (1R,2S)-2-(methoxyethoxymethoxy)-1-phenylbut-3-enyl 4-nitrobenzoate 

Downstream Products

• 474958-77-5 (1R)-1-[(1S,2R)-2-(tert-butyldimethylsilyloxy)-1-(methoxyethoxymethoxy)-2-phenylethyl]-but-3-enyl 3-phenylprop-2-enoate 
• 474958-78-6 (6R)-6-[(1S,2R)-2-(tert-butyldimethylsilyloxy)-1-(methoxyethoxymethoxy)-2-phenyl-ethyl]-5,6-dihydropyran-2-one 
• 474958-75-3 (2R,3R)-3-(tert-butyldimethylsilyloxy)-2-(methoxyethoxymethoxy)-3-phenyl-propanal 
• 473543-38-3 (1S)-1-((4S,5R)-2,2-dimethyl-5-phenyl-[1,3]-dioxolan-4-yl)-3-buten-1-ol 
• 146236-73-9 (+)-goniodiol 
• 130718-77-3 (4R,5R)-cis-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-carbaldehyde 
• 140631-03-4 (4S,5R)-4-ethenyl-2,2-dimethyl-5-phenyl-1,3-dioxolane 
• 135414-95-8 (1R,2S)-1-phenyl-3-butene-1,2-diol 
• 474958-73-1 (1R,2S)-1-(tert-butyldimethylsilyloxy)-2-(methoxyethoxymethoxy)-1-phenyl-but-3-ene 

Relevant academic research and scientific papers

Synthesis of homoallylic chiral tertiary alcohols via chelation-controlled diastereoselective nucleophilic addition on α-alkoxyketones: Application for the synthesis of the C1-C11 subunit of 8-epi-fostriecin

(Matrix presented) Chiral β-syn-alkoxyhomoallylic alcohols derived from alkoxyallylboration of aldehydes upon oxidation provided the corresponding chiral ketones. Chelation-controlled nucleophilic addition to these ketones occurred in a highly stereoselec

Stereoselective syntheses of (+)-goniodiol, (-)-8-epigoniodiol, and (+)-9-deoxygoniopypyrone via alkoxyallylboration and ring-closing metathesis

A convenient synthesis of (+)-goniodiol, (-)-8-epigoniodiol, and (+)-9-deoxygoniopypyrone has been developed via asymmetric alkoxyallylboration and ring-closing metathesis pathways.