474958-70-8

Upstream product

• 100-52-7 benzaldehyde 
• 139609-23-7 (B)-γ-2-methoxyethoxymethoxyallyldiisocampheylborane 
• 475987-09-8 (+)-B-γ-methoxyethoxymethoxyallyldiisopinocampheylborane 
• 77120-79-7 1-<(2-methoxyethoxy)methoxy>-2-propene 

Downstream Products

• 474958-79-7 (1S,2S)-1-(tert-butyldimethylsilyloxy)-2-(methoxyethoxymethoxy)-1-phenyl-but-3-ene 
• 474958-71-9 (1R,2S)-2-(methoxyethoxymethoxy)-1-phenylbut-3-enyl 4-nitrobenzoate 
• 765941-44-4 Acrylic acid (1S,2S)-2-(2-methoxy-ethoxymethoxy)-1-phenyl-but-3-enyl ester 
• 474958-77-5 (1R)-1-[(1S,2R)-2-(tert-butyldimethylsilyloxy)-1-(methoxyethoxymethoxy)-2-phenylethyl]-but-3-enyl 3-phenylprop-2-enoate 
• 474958-82-2 (1R)-1-[(1S,2S)-2-(tert-butyldimethylsilyloxy)-1-(methoxyethoxymethoxy)-2-phenyl-ethyl]-but-3-enyl-3-phenylprop-2-enoate 
• 474958-78-6 (6R)-6-[(1S,2R)-2-(tert-butyldimethylsilyloxy)-1-(methoxyethoxymethoxy)-2-phenyl-ethyl]-5,6-dihydropyran-2-one 
• 474958-83-3 (6R)-6-[(1S,2S)-2-(tert-butyldimethylsilyloxy)-1-(methoxyethoxymethoxy)-2-phenyl-ethyl]-5,6-dihydropyran-2-one 
• 474958-88-8 [(1R)-1-((4S,5S)-2,2-dimethyl-5-phenyl-[1,3]-dioxolan-4-yl)-but-3-enyl]-3-phenyl prop-2-enoate 
• 474958-75-3 (2R,3R)-3-(tert-butyldimethylsilyloxy)-2-(methoxyethoxymethoxy)-3-phenyl-propanal 
• 474958-80-0 (2R,3S)-3-(tert-butyldimethylsilyloxy)-2-(methoxyethoxymethoxy)-3-phenylpropanal 
• 474958-73-1 (1R,2S)-1-(tert-butyldimethylsilyloxy)-2-(methoxyethoxymethoxy)-1-phenyl-but-3-ene 
• 474958-89-9 (6R)-6-[(4S,5S)-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-yl]-5,6-dihydro-2H-pyran-2-one 
• 474958-86-6 (4S,5S)-2,2-dimethyl-4-phenyl-5-ethenyl[1,3]dioxolane 
• 473543-38-3 (1S)-1-((4S,5R)-2,2-dimethyl-5-phenyl-[1,3]-dioxolan-4-yl)-3-buten-1-ol 

Relevant academic research and scientific papers

Diastereoselective dihydroxylation and regioselective deoxygenation of dihydropyranones: A novel protocol for the stereoselective synthesis of C 1-C8 and C15-C21 subunits of (+)-discodermolide

Diastereoselective dihydroxylation of dihydropyranones and subsequent regioselective α-deoxygenation provides 1,3-trans-β-hydroxy-6- lactones stereoselectively. This protocol has been applied for the synthesis of C1-C8 and C15-C21 subunits of (+)-discodermolide.

Synthesis of homoallylic chiral tertiary alcohols via chelation-controlled diastereoselective nucleophilic addition on α-alkoxyketones: Application for the synthesis of the C1-C11 subunit of 8-epi-fostriecin

(Matrix presented) Chiral β-syn-alkoxyhomoallylic alcohols derived from alkoxyallylboration of aldehydes upon oxidation provided the corresponding chiral ketones. Chelation-controlled nucleophilic addition to these ketones occurred in a highly stereoselec

Stereoselective syntheses of (+)-goniodiol, (-)-8-epigoniodiol, and (+)-9-deoxygoniopypyrone via alkoxyallylboration and ring-closing metathesis

A convenient synthesis of (+)-goniodiol, (-)-8-epigoniodiol, and (+)-9-deoxygoniopypyrone has been developed via asymmetric alkoxyallylboration and ring-closing metathesis pathways.