475291-71-5

Upstream product

• 81576-71-8 methyl (3R)-3-[(benzyloxy)carbonylamino]hex-5-enoate 
• 106-95-6 allyl bromide 
• 81576-72-9 (R)-3-Benzyloxycarbonylamino-hex-5-enoic acid 
• 83436-47-9 tert-butyl (R)-3-(((benzyloxy)carbonyl)amino)hex-5-enoate 
• 179533-67-6 (R)-tert-butyl 3-((S)-4-benzyl-2-oxooxazolidine-3-carbonyl)hex-5-enoate 
• 179533-97-2 (R)-2-(2-(tert-butoxy)-2-oxoethyl)pent-4-enoic acid 
• 127474-54-8 (R)-2-(benzyloxycarbonylamino)pent-4-enoic acid 

Downstream Products

• 267230-45-5 (1R,2R)-2-aminocyclohexanecarboxylic acid methyl ester 
• 290838-42-5 methyl (1R,2R)-2-(((benzyloxy)carbonyl)amino)cyclohexane-1-carboxylate 
• 91280-45-4 (1R,6R)-6-benzyloxycarbonylaminocyclohex-3-enecarboxylic acid methyl ester 

Relevant academic research and scientific papers

Synthesis of Cyclic β-Amino Acid Esters from Methionine, Allylglycine, and Serine

Here we report a versatile ring-closing metathesis-based approach to 5-, 6-, and 7-membered cyclic β-amino esters starting with simple and readily available building blocks-methionine, allylglycine, and serine-where the nature of the amino acid determines

Synthesis of substituted cyclohexenyl-based β-amino acids by ring-closing metathesis

(equation presented) A versatile ring-closing metathesis (RCM) approach has been developed for the preparation of cis and trans cyclohexenyl-based β-amino acids that are either unsubstituted (3) or substituted (10 and 12) at the α-position.