475641-59-9

Upstream product

• 83938-00-5 ((2R,3S,6S)-3-acetoxy-6-cyano-3,6-dihydro-2H-pyran-2-yl)methyl acetate 
• 475641-84-0 Chloro-methanesulfonic acid (2R,4S,5R)-5-[(1S,2R)-2-(tert-butyl-dimethyl-silanyloxy)-1-(tert-butyl-dimethyl-silanyloxymethyl)-pent-4-enyloxy]-2-phenyl-[1,3]dioxan-4-ylmethyl ester 
• 475641-86-2 {(2R,4S,5R)-5-[(1S,2R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-(tert-butyl-dimethyl-silanyloxymethyl)-pent-4-enyloxy]-2-phenyl-[1,3]dioxan-4-yl}-acetonitrile 
• 475641-88-4 {(2R,4S,5R)-5-[(1S,2R)-2-(tert-Butyl-dimethyl-silanyloxy)-1-(tert-butyl-dimethyl-silanyloxymethyl)-pent-4-enyloxy]-2-phenyl-[1,3]dioxan-4-yl}-acetaldehyde 
• 475641-82-8 Chloro-methanesulfonic acid (2R,4S,5R)-5-((4R,5S)-4-allyl-2-phenyl-[1,3,2]dioxaborinan-5-yloxy)-2-phenyl-[1,3]dioxan-4-ylmethyl ester 
• 475641-63-5 (2R,4aR,6R,7R,8S,8aR)-7,8-Bis-(tert-butyl-dimethyl-silanyloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine-6-carbonitrile 
• 475641-64-6 (2R,4aR,6S,7R,8S,8aR)-7,8-Bis-(tert-butyl-dimethyl-silanyloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine-6-carbaldehyde 
• 475641-72-6 [(2R,4S,5R)-5-((4R,5S)-4-Allyl-2-phenyl-[1,3,2]dioxaborinan-5-yloxy)-2-phenyl-[1,3]dioxan-4-yl]-methanol 
• 475641-68-0 (2R,4aR,6R,7S,8R,8aS)-6-((R)-1-Hydroxy-but-3-enyl)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol 
• 475641-70-4 (2S,3R)-2-((2R,4S,5R)-4-Hydroxymethyl-2-phenyl-[1,3]dioxan-5-yloxy)-hex-5-ene-1,3-diol 
• 475641-62-4 (2R,4aR,6R,7S,8R,8aS)-7,8-Dihydroxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine-6-carbonitrile 
• 2873-29-2 D-glucal triacetate 
• 88180-37-4 4,6-O-Benzylidene-2,3-dideoxy-α-D-erythro-hex-2-enopyranosyl cyanide 
• 88180-36-3 2,3-dideoxy-α-D-erythro-hex-2-enopyranosyl cyanide 

Downstream Products

• 792919-97-2 (1R,3S,4R,6Z,9S,11R)-4-(tert-butyldimethylsilyloxy)-3-hydroxymethyl-11-phenyl-2,10,12-trioxabicyclo[7.4.0]tridec-6-ene 
• 876288-75-4 (1R,3S,4R,6Z,9S,11S)-3-hydroxymethyl-11-phenyl-2,10,12-trioxabicyclo[7.4.0]tridecan-6-en-4-ol 
• 876288-77-6 (2R,3S,5Z,8R,9S)-8-benzyloxy-9-benzyloxymethyl-2-hydroxymethyl-2,3,4,7,8,9-hexahydrooxonin-3-ol 
• 876288-76-5 (1R,3S,4R,6Z,9S,11S)-4-benzyloxy-3-benzyloxymethyl-11-phenyl-2,10,12-trioxabicyclo[7.4.0]tridecan-6-ene 
• 876288-82-3 (2R,3S,5Z,8R,9S)-3-benzyloxy-2-benzyloxymethyl-8-(tret-butyldimethylsilyloxy)-9-(but-2'-ynyl)-2,3,4,7,8,9-hexahydrooxonin 
• 876288-68-5 (2R,3S,5Z,8R,9S,2'E)-3-benzyloxy-2-benzyloxymethyl-8-(tret-butyldimethylsilyloxy)-9-(3'-iodo-but-2'-ynyl)-2,3,4,7,8,9-hexahydrooxonin 
• 876288-81-2 (2R,3S,5Z,8R,9S)-[8-benzyloxy-9-benzyloxymethyl-3-(tret-butyldimethylsilyloxy)-2,3,4,7,8,9-hexahydrooxonin-2-yl]methyl trifluoromethanesulfonate 
• 876288-65-2 2-[1-benzyloxy-2-(8-benzyloxy-9-benzyloxymethyl-3-hydroxy-2,3,4,7,8,9-hexahydro-oxonin-2-yl)-ethyl]-7-(4-bromo-benzyloxy)-6-(4-bromo-benzyloxymethyl)-2,9-dimethyl-octahydro-1,5-dioxa-benzocycloocten-3-one 
• 876288-89-0 2-[8-benzyloxy-9-benzyloxymethyl-3-(tert-butyl-dimethyl-silanyloxy)-2,3,4,7,8,9-hexahydro-oxonin-2-yl]-1-[7-(4-bromo-benzyloxy)-6-(4-bromo-benzyloxymethyl)-3-hydroxy-2,9-dimethyl-decahydro-1,5-dioxa-benzocycloocten-2-yl]-ethanone 
• 876288-91-4 2-{2-[8-benzyloxy-9-benzyloxymethyl-3-(tert-butyl-dimethyl-silanyloxy)-2,3,4,7,8,9-hexahydro-oxonin-2-yl]-1-hydroxy-ethyl}-7-(4-bromo-benzyloxy)-6-(4-bromo-benzyloxymethyl)-2,9-dimethyl-decahydro-1,5-dioxa-benzocycloocten-3-ol 
• 876288-90-3 2-{2-[8-benzyloxy-9-benzyloxymethyl-3-(tert-butyl-dimethyl-silanyloxy)-2,3,4,7,8,9-hexahydro-oxonin-2-yl]-1-hydroxy-ethyl}-7-(4-bromo-benzyloxy)-6-(4-bromo-benzyloxymethyl)-2,9-dimethyl-decahydro-1,5-dioxa-benzocycloocten-3-ol 
• 876288-95-8 2-{1-benzyloxy-2-[8-benzyloxy-9-benzyloxymethyl-3-(tert-butyl-dimethyl-silanyloxy)-2,3,4,7,8,9-hexahydro-oxonin-2-yl]-ethyl}-7-(4-bromo-benzyloxy)-6-(4-bromo-benzyloxymethyl)-2,9-dimethyl-decahydro-1,5-dioxa-benzocycloocten-3-ol 
• 876288-96-9 2-{1-benzyloxy-2-[8-benzyloxy-9-benzyloxymethyl-3-(tert-butyl-dimethyl-silanyloxy)-2,3,4,7,8,9-hexahydro-oxonin-2-yl]-ethyl}-7-(4-bromo-benzyloxy)-6-(4-bromo-benzyloxymethyl)-2,9-dimethyl-octahydro-1,5-dioxa-benzocycloocten-3-one 
• 876288-84-5 5-[8-benzyloxy-9-benzyloxymethyl-3-(tert-butyl-dimethyl-silanyloxy)-2,3,4,7,8,9-hexahydro-oxonin-2-yl]-1-[7-(4-bromo-benzyloxy)-8-(4-bromo-benzyloxymethyl)-3-(4-methoxy-benzyloxy)-5-methyl-oxocan-2-yl]-3-methyl-pent-3-en-2-ol 

Relevant academic research and scientific papers

Syntheses of the D-, E-, F-, and I-ring parts of ciguatoxin by a common strategy starting from tri-O-acetyl-D-glucal

Chiral medium-sized monocyclic ethers corresponding to the D-, E-, F-, and I-ring parts of ciguatoxin have been synthesized from tri-O-acetyl-D-glucal through a common synthetic route involving ring-closing olefin metathesis.