476172-53-9Relevant academic research and scientific papers
Synthesis of new phosphino-amines, their metal complexes and their application in catalysis
Izubiri, Mireia Rodriguez,Slawin, Alexandra M. Z.,Cole-Hamilton, David,Woollins, J. Derek
, p. 117 - 120 (2001)
The compounds (C6H4O2P)2N∩N, (Ph2P)2N∩N and (1Pr2P)2N∩N (where N∩N = homopiperazine) prepared by the condensation reaction of diamines with chlorophosphines in presence of Et3N have been tested in Rhodium catalysed hydroformylation and Palladium allylic alkylation. Also a variety of late transition metal complexes with Pt(II), Pd(II), Au(I) and Mo(0) were prepared.
P-N bound formation as a route to a highly electron rich bidentate phosphine ligand and its application in homogenous catalysis
Zubiri, Mireia Rodriguez i,Clarke, Matthew L.,Foster, Douglas F.,Cole-Hamilton, David J.,Slawin, Alexandre M. Z.,Woollins, J. Derek
, p. 969 - 971 (2007/10/03)
Bis-phosphines containing two electron donating alkyl groups linked by a diamine backbone are extremely electron rich ?-donor bidentate ligands and have been used, along with phenyl and catechol substituted bis-phosphinoamines, to study hydroformylation reactions.
