Synthesis of new phosphino-amines, their metal complexes and their application in catalysis

Article abstract of DOI:10.1080/10426500108546604

The compounds (C₆H₄O₂P)₂N∩N, (Ph₂P)₂N∩N and (¹Pr₂P)₂N∩N (where N∩N = homopiperazine) prepared by the condensation reaction of diamines with chlorophosphines in presence of Et₃N have been tested in Rhodium catalysed hydroformylation and Palladium allylic alkylation. Also a variety of late transition metal complexes with Pt(II), Pd(II), Au(I) and Mo(0) were prepared.

Full text of DOI:10.1080/10426500108546604

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Phosphorus, Sulfur,
and Silicon and the
Related Elements
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gpss20
Synthesis of
New Phosphino-
Amines, their Metal
Complexes and
their Application in
Catalysis
Mireia Rodriguez Izubiri ,
Alexandra M. Z. Slawin , David
Cole-Hamilton & J. Derek Woollins
a Department of Chemistry ,
University of St Andrews , Fife,
Scotland, KY16 9ST
b Department of Chemistry ,
University of St Andrews , Fife,
Scotland, KY16 9ST
c Department of Chemistry ,
University of St Andrews , Fife,
Scotland, KY16 9ST

d Department of Chemistry ,
University of St Andrews , Fife,
Scotland, KY16 9ST
Published online: 02 Apr 2008.
To cite this article: Mireia Rodriguez Izubiri , Alexandra M. Z.
Slawin , David Cole-Hamilton & J. Derek Woollins (2001) Synthesis of
New Phosphino-Amines, their Metal Complexes and their Application
in Catalysis, Phosphorus, Sulfur, and Silicon and the Related
Elements, 169:1, 117-120, DOI: 10.1080/10426500108546604
To link to this article: http://
dx.doi.org/10.1080/10426500108546604
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