476687-78-2

Upstream product

• 100-52-7 benzaldehyde 
• 78-79-5 isoprene 
• 39652-50-1 5-hydroxy-3-methyl-5-phenyl-pent-2-enoic acid methyl ester 
• 19041-17-9 methyl 4-bromo-3-methylbut-2-enoate 

Downstream Products

• 201145-41-7 (E)-5-hydroxy-3-methyl-5-phenyl-pent-2-enal 
• 1075200-35-9 (E)-3-methyl-5-phenylpent-2-ene-1,5-diol diacetate 
• 476688-17-2 (1R,3S)-3-methyl-1-phenylpentane-1,5-diol 
• 149713-23-5 (2S,2S)-4-methyl-2-phenyl-tetrahydro-2H-pyran 
• 149713-23-5 (2R,2S)-4-methyl-2-phenyl-tetrahydro-2H-pyran 

Relevant academic research and scientific papers

Diastereoselective construction of functionalized homoallylic alcohols by Ni-catalyzed diboron-promoted coupling of dienes and aldehydes

The nickel-catalyzed reaction of carbonyls and dienes was accomplished in a regio- and stereoselective fashion employing a stoichiometric amount of bis(pinacolato)diboron. This reductive coupling furnishes an allyl boronic ester as the reaction product, a compound which was readily converted to the derived allylic alcohol by oxidative workup. Copyright

Biocatalyzed preparation of the optically enriched stereoisomers of 4-methyl-2-phenyl-tetrahydro-2H-pyran (Doremox)

The four stereoisomers of the rose oxide analogue Doremox were prepared in enantiomerically enriched form by enantiospecific bakers' yeast reduction of suitable derivatives and by lipase-mediated kinetic resolution of diol precursors.