477-75-8Relevant articles and documents
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Craig,Wilcox
, p. 1619 (1959)
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Facile Net Loss of a Carbon Atom from a Constrained Intermediate
Tivakornpannarai, Supanna,Waali, Edward E.
, p. 6058 - 6059 (1986)
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Synthesis, Structure, and Complexation Properties of a C3-Symmetrical Triptycene-Based Anion Receptor: Selectivity for Dihydrogen Phosphate
Granda, Jaroslaw M.,Grabowski, Jakub,Jurczak, Janusz
, p. 5882 - 5885 (2015)
A new anion binding motif based on triptycene core has been synthesized from 2,7,14-trinitrotriptycene. Its well-defined binding pocket allowed for the selective recognition and sensing of dihydrogen phosphate in DMSO-d6 + 0.5% H2O.
Microwave-induced covalent functionalization of few-layer graphene with arynes under solvent-free conditions
Sulleiro,Quiroga,Pe?a,Pérez,Guitián,Criado,Prato
supporting information, p. 2086 - 2089 (2018/03/06)
A non-conventional modification of exfoliated few-layer graphene (FLG) with different arynes under microwave (MW) irradiation and solvent-free conditions is reported. The described approach allows reaching fast, efficient and mild covalent functionalization of FLG.
Pseudocyclic Arylbenziodoxaboroles: Efficient Benzyne Precursors Triggered by Water at Room Temperature
Yoshimura, Akira,Fuchs, Jonathan M.,Middleton, Kyle R.,Maskaev, Andrey V.,Rohde, Gregory T.,Saito, Akio,Postnikov, Pavel S.,Yusubov, Mekhman S.,Nemykin, Victor N.,Zhdankin, Viktor V.
supporting information, p. 16738 - 16742 (2017/12/02)
New organohypervalent iodine compounds, arylbenziodoxaborole triflates, were prepared from 1-acetoxybenziodoxaboroles and arenes by treatment with trifluoromethanesulfonic acid under mild conditions. Single crystal X-ray crystallography of these compounds revealed a pseudocyclic structure with a short intramolecular interaction of 2.698 to 2.717 ? between oxygen and iodine in the benziodoxaborole ring. These new pseudocyclic aryliodonium salts readily generate aryne intermediates upon treatment with water at room temperature. The generated aryne intermediates react with various substrates to give the corresponding aryne adducts in moderate to good yields. Furthermore, the new benzyne precursors can also work as arylating reagents towards aromatic rings. The aryne intermediates generated from arylbenziodoxaborole triflates selectively react with tert-butyl phenol forming products of ortho arylation in moderate yields.