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477178-18-0

[2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2Cl is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 477178-18-0 Structure

  • Basic information

    1. Product Name: [2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2Cl
    2. Synonyms:
    3. CAS NO:477178-18-0
    4. Molecular Formula:
    5. Molecular Weight: 529
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 477178-18-0.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: [2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2Cl(CAS DataBase Reference)
    10. NIST Chemistry Reference: [2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2Cl(477178-18-0)
    11. EPA Substance Registry System: [2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru(CO)2Cl(477178-18-0)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 477178-18-0(Hazardous Substances Data)

477178-18-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 477178-18-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 4,7,7,1,7 and 8 respectively; the second part has 2 digits, 1 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 477178-18:
(8*4)+(7*7)+(6*7)+(5*1)+(4*7)+(3*8)+(2*1)+(1*8)=190
190 % 10 = 0
So 477178-18-0 is a valid CAS Registry Number.

477178-18-0Relevant articles and documents

Protonated aminocyclopentadienyl ruthenium hydride reduction of benzaldehyde and the conversion of the resulting ruthenium triflate to a ruthenium hydride with H2 and base

Casey, Charles P.,Vos, Thomas E.,Singer, Steven W.,Guzei, Ilia A.

, p. 5038 - 5046 (2008/10/08)

Reaction of N-phenyl-2,5-dimethyl-3,4-diphenylcyclopenta-2,4-dienimine (6) with Ru3CO12 formed two isomers of {[2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru (CO)(μ-CO)}2 (8-trans and 8-cis). Photolysis of 8 under a H2 atmosphere led to the formation of the aminocyclopentadienyl ruthenium hydride [2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru( CO)2H (9-H). 9-H reduced benzaldehyde slowly at 75 °C to give benzyl alcohol and 8. Protonation of 9-H with triflic acid produced {[2,5-Me2-3,4-Ph2(η5-C4CNH2 Ph)]Ru(CO)2H}OTf (11-H), which reacted rapidly with benzaldehyde at -80 °C to give benzyl alcohol and [2,5-Me2-3,4-Ph2(η5-C4CNHPh)]Ru( CO)2OTf (9-OTf). Reaction of 9-OTf with H2 and base led to the re-formation of 9-H. These reactions provide the transformations required for a catalytic cycle for hydrogenation of aldehydes.

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