477761-64-1Relevant academic research and scientific papers
Synthesis and characterization of binuclear Zn(II)-cyclen complexes bridged by α,ω-bis(4-methylphenoxy) alkanes
Wan, Fuxian,Li, Changcheng,Jiang, Lin,Li, Ying
, p. 2085 - 2096 (2013/02/23)
A series of novel α,ω-bis(4-methylphenoxy) alkane functionalized cyclen ligands were synthesized by the nucleophilic substitution reaction of 1,4,7-tris(tert-butyloxycarbonyl)-1,4,7,10-tetraazacyclododecane and α,ω-bis(4-bromomethylphenoxy) alkanes. The corresponding dimeric Zn(II)-cyclen complexes were obtained by reaction of these ligands with Zn(ClO4)2·6H2O. Ligands and complexes were characterized by FT-IR, 1H NMR, and elemental analysis. Springer Science+Business Media B.V. 2012.
Analysis and improvement of an anion-templated rotaxane synthesis
Schalley, Christoph A.,Silva, Gabriele,Nising, Carl Friedrich,Linnartz, Petra
, p. 1578 - 1596 (2007/10/03)
A series of new rotaxanes with axles different in length was prepared. Following the synthetic protocol utilizing a known anion template effect (Scheme 1), surprisingly low yields in the order of 2 - 5% were obtained (Scheme 3), which furthermore signific
Molecular Recognition of Neutral Molecules by Metalloclefts: Synthesis, X-ray Structure, 1H NMR Spectroscopy, Electrochemistry, and Molecular Modeling
Doorn, Arie R. van,Bos, Martinus,Harkema, Sybolt,Eerden, Johan van,Verboom, Willem,Reinhoudt, David N.
, p. 2371 - 2380 (2007/10/02)
Metalloclefts 2 and 10a-b and metallomacrocycles 7a-c possessing a Lewis acidic uranyl cation were synthesized from the corresponding aldehydes.The complexation of these compounds with neutral molecules was assessed by 1H NMR spectroscopy, X-ray structure
