478015-73-5Relevant academic research and scientific papers
Tandem one pot asymmetric conjugate addition-vinyl inflate formation - Cross coupling methodology
Suarez, Rosa M.,Pena, Diego,Minnaard, Adriaan J.,Feringa, Ben L.
, p. 729 - 731 (2005)
Optically active vinyl triflate were obtained and employed in a series of one pot metal-catalyzed tandem asymmetric transformations. These vinyl triflates were used in Pd-catalyzed cross-coupling reactions with organometallic reagents to provide chiral ol
Tandem Asymmetric Conjugate Addition-Silylation of Enantiomerically Enriched Zinc Enolates. Synthetic Importance and Mechanistic Implications
Knopff, Oliver,Alexakis, Alexandre
, p. 3835 - 3837 (2007/10/03)
(Matrix Presented) The zinc enolates, resulting from the copper-catalyzed enantioselective conjugate addition of dialkyl zinc reagents to cyclic and acyclic enones, could be trapped, quantitatively, as silyl enol ethers with TMSOTf in apolar solvents or w
