478283-16-8Relevant academic research and scientific papers
Light- and Manganese-Initiated Borylation of Aryl Diazonium Salts: Mechanistic Insight on the Ultrafast Time-Scale Revealed by Time-Resolved Spectroscopic Analysis
Firth, James D.,Hammarback, L. Anders,Burden, Thomas J.,Eastwood, Jonathan B.,Donald, James R.,Horbaczewskyj, Chris S.,McRobie, Matthew T.,Tramaseur, Adam,Clark, Ian P.,Towrie, Michael,Robinson, Alan,Krieger, Jean-Philippe,Lynam, Jason M.,Fairlamb, Ian J. S.
, p. 3979 - 3985 (2021)
Manganese-mediated borylation of aryl/heteroaryl diazonium salts emerges as a general and versatile synthetic methodology for the synthesis of the corresponding boronate esters. The reaction proved an ideal testing ground for delineating the Mn species responsible for the photochemical reaction processes, that is, involving either Mn radical or Mn cationic species, which is dependent on the presence of a suitably strong oxidant. Our findings are important for a plethora of processes employing Mn-containing carbonyl species as initiators and/or catalysts, which have considerable potential in synthetic applications.
TOPICAL ANTIANDROGENIC STEROIDS
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Page 29-31, (2010/02/09)
Steroidal antiandrogens and pharmaceutical compositions thereof, are used for reduction of the risk of developing, or for treatment of, androgen-dependent skin related diseases. In preferred embodiments, the antiandrogen EM-3180 is used for reduction of t
New efficient pathway for the synthesis of 3-aminoestrone
Radu, Ioan-Iosif,Poirier, Donald,Provencher, Louis
, p. 7617 - 7619 (2007/10/03)
3-Aminoestrone, a non-natural C-18 steroid, was synthesized by the classical and by a new efficient pathway, the latter using benzophenone imine as an ammonia equivalent in the palladium(0)-catalysed amination of estrone-triflate. This methodology circumv
