478703-77-4Relevant academic research and scientific papers
Total synthesis of polycephalin C and determination of the absolute configurations at the 3′′,4′′ ring junction
Longbottom, Deborah A.,Morrison, Angus J.,Dixon, Darren J.,Ley, Steven V.
, p. 2786 - 2790 (2007/10/03)
Only through total synthesis could the absolute configuration of the 3′′R,4′′R ring junction of the polyenoltetramic acid polycephalin C (1) be unambiguously established. Key features of the synthesis include a double Swern oxidation, double Stille coupli
The absolute configuration of polycephalin C from the slime mold Physarum polycephalum (Myxomycetes)
Blumenthal, Florian,Polborn, Kurt,Steffan, Bert
, p. 8433 - 8437 (2007/10/03)
The absolute configuration of polycephalin C (1) isolated from plasmodia of the slime mold Physarum polycephalum is supposed to be 3″R,4″R as found by comparison of CD spectra of the natural product polycephalin C (1) and CD spectra of synthetic bis-benzo
