618093-67-7Relevant academic research and scientific papers
Total synthesis of the polyenoyltetramic acid polycephalin C
Longbottom, Deborah A.,Morrison, Angus J.,Dixon, Darren J.,Ley, Steven V.
, p. 6955 - 6966 (2007/10/03)
The total synthesis of the polyenoyltetramic acid polycephalin C is described. Key steps of the synthesis include a double Swern oxidation, double Takai reaction and a double Stille reaction. In addition, the absolute stereochemistry of the ring junction
Total synthesis of polycephalin C and determination of the absolute configurations at the 3′′,4′′ ring junction
Longbottom, Deborah A.,Morrison, Angus J.,Dixon, Darren J.,Ley, Steven V.
, p. 2786 - 2790 (2007/10/03)
Only through total synthesis could the absolute configuration of the 3′′R,4′′R ring junction of the polyenoltetramic acid polycephalin C (1) be unambiguously established. Key features of the synthesis include a double Swern oxidation, double Stille coupli
