478800-45-2

Upstream product

• 478800-17-8 (2R)-1-(tert-butyldiphenylsilanyloxy)-6-(tetrahydropyran-2-yloxy)hex-4-yn-2-ol 
• 107033-46-5 (R)-(tert-butyldiphenylsilyloxy)methyloxirane 

Downstream Products

• 1063674-29-2 (2R)-1-tert-butyldiphenylsilyloxy-2,6-hexanediol 
• 343981-88-4 tert-butyldiphenyl (((2R,6R)-6-isopropoxy-3,6-dihydro-2H-pyran-2-yl)methoxy)silane 
• 478800-46-3 6-(tert-butyl-diphenyl-silanyloxymethyl)-5,6-dihydro-2H-pyran-2-ol 
• 478800-19-0 (E)-(R)-6-(tert-Butyl-diphenyl-silanyloxy)-5-hydroxy-hex-2-enal 
• 410523-53-4 (2'R,6'R,1E,3Z,5R)-(+)-7-tert-butyldiphenylsilyloxy-1-(5',6'-dihydro-2'H-2'-isopropoxypyran-6'-yl)-3-ethyl-5-methylhepta-1,3-diene 
• 478800-18-9 (Z)-(2R)-6-(tert-butyldiphenylsilanyloxy)hex-2-ene-1,5-diol 

Relevant academic research and scientific papers

Total synthesis of (-)-histrionicotoxin 285A and (-)- perhydrohistrionicotoxin

(Chemical Equation Presented) Starting from commercially available (S)-glycidol, and via a common intermediate, the total synthesis of (-)-histrionicotoxin 285A and (-)-perhydrohistrionicotoxin has been achieved. Key to this synthesis was the efficient co

Oxabicyclo[3.2.1]oct-6-enes as templates for the stereoselective synthesis of polypropionates: Total synthesis of callystatin a and C19-epi-callystatin A

The total synthesis of the polyketide natural product callystatin A and its novel analog C19-epi-callystatin A is described. Our strategy features the use of an enantiomerically pure oxabicyclo[3.2.1]oct-6-ene as a template for the stereocontrolled preparation of the C15-C21 polypropionate region.