4792-92-1Relevant academic research and scientific papers
Convenient synthesis of copper (I) thiolates and related compounds
Nguyen, Lynda M.,Dellinger, Megan E.,Lee, Jeffrey T.,Quinlan, Ronald A.,Rheingold, Arnold L.,Pike, Robert D.
, p. 1331 - 1336 (2005)
Copper (I) salts of various anions including thiolates, diethyl dithiocarbamate, diethyl dithiophosphate, trithiocyanurate, 1-cyano-3- methylisothiourea, 2-aminothiazole, and tetrakis(1-imidazolyl)borate are conveniently synthesized by reducing copper (II) sulfate in aqueous ammonia. The addition of phosphine ligands to several of the products is demonstrated, and the crystal structure of [Cu2(MBT)2(DPPE)3] ? Et2O (MBT = 2-mercaptobenzothiazolate, DPPE = 1,2-bis(diphenylphosphino)ethane) is reported.
