479400-47-0Relevant articles and documents
Missing cyclization pathways and new rearrangements unveiled in the gold(I) and platinum(II)-catalyzed cyclization of 1,6-enynes
Ferrer, Catalina,Raducan, Mihai,Nevado, Cristina,Claverie, Christelle K.,Echavarren, Antonio M.
, p. 6306 - 6316 (2008/02/05)
Cyclopropyl metal carbenes formed in the 6-endo-dig cyclization may evolve to form seven-membered ring intermediates. This has been achieved for the first time by using highly electrophilic platinum(II) and gold(I) complexes. Gold(I) also triggers a remar