479627-69-5

Upstream product

• 79265-44-4 Methyl-(E)-2-methyl-4-phenyl-2-buteonate 
• 124-63-0 methanesulfonyl chloride 
• 479627-63-9 C₁₁H₁₂⁽²⁾H₂O 

Downstream Products

• 274918-70-6 (E)-1-phenyl-3-methyl-4,4,4-trideuterio-2-butene 

Relevant academic research and scientific papers

Site specificity in the photooxidation of some trisubstituted alkenes in thionin-supported zeolite Na-Y. On the role of the alkali metal cation

(Matrix Presented) The less substituted side of some geminal dimethyl trisubstituted alkenes becomes significantly more reactive if photooxygenation takes place in thionin-supported zeolite Na-Y. These results are mainly attributed to a synergistic intera

Control of regioselectivity by the lone substituent through steric and electronic effects in the nitrosoarene ene reaction of deuterium-labeled trisubstituted alkenes

For the ene reaction of 4-nitronitrosobenzene (ARNO) with a variety of primary and secondary lone alkyl-substituted substrates, the twix/twin regioselectivity is constant at about 85:15. In contrast, for the lone tert-butyl group and for lone aryl substituents, the twix regioisomer is obtained exclusively. These regioselectivities have been rationalized in terms of steric interactions and coordination between the enophile and the substrates in the transition states of the first reaction step.