4808-04-2

Basic information

• Product Name: 5-(2,6,6-trimethylcyclohex-1-enyl)penta-2,4-dien-1-ol
• Synonyms: 5-(2,6,6-trimethylcyclohex-1-enyl)penta-2,4-dien-1-ol
• CAS NO: 4808-04-2
• Molecular Weight: 206.328
• Mol File: 4808-04-2.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 5-(2,6,6-trimethylcyclohex-1-enyl)penta-2,4-dien-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 5-(2,6,6-trimethylcyclohex-1-enyl)penta-2,4-dien-1-ol(4808-04-2)
• EPA Substance Registry System: 5-(2,6,6-trimethylcyclohex-1-enyl)penta-2,4-dien-1-ol(4808-04-2)

Safety Data

• Hazardous Substances Data: 4808-04-2(Hazardous Substances Data)

Upstream product

• 53018-97-6 (E)-3-(2,6,6-Trimethyl-cyclohex-1-enyl)-propenal 
• 14393-45-4 (E)-3-(2,6,6-trimethylcyclohex-1-enyl)acrylic acid 
• 79-77-6 (E)-β-ionone 
• 85458-25-9 5,5-dimethoxy-1-(2,6,6-trimethyl-cyclohex-1-enyl)-pent-1-en-3-one 
• 472-66-2 (2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde 
• 82994-41-0 (E)-3-(tri-n-butylstannyl)-2-propen-1-ol 
• 475673-41-7 (E)-2-(2,6,6-trimethylcyclohexen-1-yl)ethenyl nonafluorobutanesulfonate 
• 303779-99-9 (E)-2-(2,6,6-trimethylcyclohexen-1-yl)-ethenyl (trifluoromethyl)sulfonate 
• 4808-00-8 (2E,4E)-5-(2’,6’,6’-trimethylcyclohex-1’-en-1’-yl)-penta-2,4-dienenal 
• 4808-03-1 ethyl (2E,4E)-5-(2,6,6-trimethylcyclohex-1-en-1-yl)penta-2,4-dienoate 

Downstream Products

• 5507-79-9 methyl 9,13-bisdesmethylretinoate 
• 5358-27-0 all-trans-9-Desmethyl-vitamin-A-saeure 
• 4834-01-9 9-demethylretinol 
• 24336-21-8 9-(2,6,6-trimethylcyclohex-1-enyl)nona-2,4,6,8-tetraenal 
• 52152-31-5 11-cis-9-Demethylretinal 
• 24336-19-4 all-trans-9-desmethyltretinal 
• 52152-32-6 9-cis-9-demethylretinal 
• 4808-00-8 (2E,4E)-5-(2’,6’,6’-trimethylcyclohex-1’-en-1’-yl)-penta-2,4-dienenal 

Relevant articles and documents

Palladium-catalyzed coupling reaction of an enol nonaflate with (vinyl)tributylstannanes and acetylenes: A highly stereoselective synthesis of 8,18-13C2-labeled retinal

Here we report that enol nonaflates exhibit higher reactivity than the corresponding enol triflates in palladium-catalyzed cross-coupling reactions with various (vinyl)tributylstannanes and acetylenes. We also highlight the reaction of a vinyl nonaflate,

Preparation of 11,14-epoxy-bridged and isomeric chain-demethylated retinals. 13-Demethyl-11,14-epoxy-, 9-demethyl-, 13-demethyl- and 9,13-bisdemethyl-retinals

9-Cis- and all-trans-13-demethyl-11,14-epoxyretinyl acetate were prepared via a Wittig coupling between β-ionylidenetriphenylphosphonium bromide (1) and 5-(acetoxymethyl)furfural.Saponification of these acetates, subsequent oxidation and HPLC separation a