480997-11-3Relevant academic research and scientific papers
Cooperative catalysis by tertiary amino-thioureas: Mechanism and basis for enantioselectivity of ketone cyanosilylation
Zuend, Stephan J.,Jacobsen, Eric N.
, p. 15872 - 15883 (2007)
The mechanism of the enantioselective cyanosilylation of ketones catalyzed by tertiary amino-thiourea derivatives was investigated using a combination of experimental and theoretical methods. The kinetic analysis is consistent with a cooperative mechanism
