48186-94-3Relevant academic research and scientific papers
Synthesis and Characterisation of (Acetylacetonato) (2-aminobenzoato) Complexes of Oxovanadium(IV), Manganese(II), Cobalt(II), Nickel(II) and Zinc(II)
Aggarwal, R. C.,Bala, Rashmi,Prasad, R. L.
, p. 568 - 571 (2007/10/02)
Ternary complexes of the formula M(acac)(ab).nL have been prepared and their structures elucidated on the basis of analytical, molar conductance, magnetic susceptibility, electronic, ESR and infrared spectral data.The molar conductance data in DMF indicate non-ionic nature of all the complexes.IR studies indicate uninegative bidentate chelating behaviour of both the ligands.Electronic spectra in conjunction with magnetic moments and ESR spectra (in case of copper and vanadyl complexes) are in accord with octahedral environment around the metal ions in all the complexes except Cu(II) and Zn(II) complexes which have been shown to possess square-planar and tetrahedral geometries respectively.Magnetic moments, electronic and IR studies indicate that stereochemistry around the central metal ions remains unaltered in going from hydrated complexes to the corresponding anhydrous complexes.
