482636-09-9

Basic information

• Product Name: ethyl 2-[dimethyl(4-methoxyphenyl)silyl]ethanoate
• Synonyms: ethyl 2-[dimethyl(4-methoxyphenyl)silyl]ethanoate
• CAS NO: 482636-09-9
• Molecular Weight: 252.386
• Mol File: 482636-09-9.mol

Chemical Properties

• CAS DataBase Reference: ethyl 2-[dimethyl(4-methoxyphenyl)silyl]ethanoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 2-[dimethyl(4-methoxyphenyl)silyl]ethanoate(482636-09-9)
• EPA Substance Registry System: ethyl 2-[dimethyl(4-methoxyphenyl)silyl]ethanoate(482636-09-9)

Safety Data

• Hazardous Substances Data: 482636-09-9(Hazardous Substances Data)

Upstream product

• 623-73-4 diazoacetic acid ethyl ester 
• 1432-38-8 (p-methoxyphenyl)dimethylsilane 
• 14774-77-7 p-methoxyphenyllithium 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 17903-46-7 [(4-methoxyphenyl)dimethylsilyl]methyl chloride 
• 541-41-3 chloroformic acid ethyl ester 
• 2372-33-0 chlorodimethyl(4-methoxyphenyl)silane 
• 105-36-2 ethyl bromoacetate 

Downstream Products

• 152879-06-6 1-chloro-2-[(4-methoxyphenyl)dimethylsilyl]ethane 
• 37110-65-9 2-[(4-methoxyphenyl)dimethylsilyl]ethanol 

Relevant articles and documents

The preparation of polymer beads by photocationic suspension co-polymerisation of 2-(arylsilyl)ethyl vinyl ethers

Polymer beads have been prepared by photocationic suspension polymerisation of 2-(aryldimethyl)silyl ethers in perfluorooctane in the course of our studies on polymer-supported desymmetrisation of 1-silacyclohexa-2,5-dienes. Good yields of 100-200 μm beads of satisfactory shape have been obtained using a perfluorinated co-polymer as stabilising agent. These beads have no permanent porosity although they have a high nominal cross-linking level. Their swelling in common organic solvents is comparable with those of Merrifield or TentaGel gel-type resins.

Au Nanoparticle-Catalyzed Insertion of Carbenes from α-Diazocarbonyl Compounds into Hydrosilanes

Supported Au nanoparticles on TiO2 catalyze the insertion of carbenes from α-diazocabonyl compounds into hydrosilanes. It is proposed that the transformation involves two modes of catalytic activation: formation of nucleophilic Au carbenes on the surface of nanoparticle via expulsion of N2 and activation of the Si-H bond of hydrosilane on Au nanoparticle, followed by coupling of the chemisorbed species. No external ligands or additives are required, while the process is purely heterogeneous, thus allowing the recycling and reuse of the catalyst.

The Yukawa-Tsuno relationship for the β-silicon effect in the solvolysis rates of 2-(aryldimethylsilyl)ethyl chlorides

Solvolysis rates of 2-(aryldimethylsilyl)ethyl chlorides were determined conductimetrically in 60% (v/v) aqueous ethanol. The effects of aryl substituents at the silyl atom on the solvolysis rates at 50°C were correlated with essentially nonresonant σ parameters of r = 0:10 in terms of Yukawa-Tsuno (Y-T) Eq. 1, giving a ρ value of -1:75. Such a high ρ value may be regarded as the effect of aryl ring on the bridged Si in the rate-determining step. The Si-bridging is consistent with the fact that the solvolysis of the unsubstituted substrate with d2-labeled ethylene moiety gave substitution products with label scrambling. The arylsilyl substituent effects were likewise analyzed for several relevant sets of β-silyl systems in order to ascertain significant variations of ρ values from system to system; Y-T Eq. 1 correlated quite excellently with essentially nonresonant sigmas of negligible resonance demand (r ? 0:10), to exhibit significant variations of ρ from -1:75 to -0:95.