4836-09-3

Usage

Uses

Used in Polymer and Copolymer Production:
2-(methylthio)ethyl acrylate is used as a monomer for the production of polymers and copolymers, contributing to the formation of various materials with specific properties. Its ability to polymerize under certain conditions makes it a valuable component in the creation of plastics, coatings, and adhesives.
Used in Chemical Industry:
In the chemical industry, 2-(methylthio)ethyl acrylate is used as a reactive intermediate for the synthesis of various chemical products. Its reactivity allows for the development of new compounds with unique characteristics, expanding the range of applications in different sectors.
Used in Research and Development:
2-(methylthio)ethyl acrylate is utilized in research and development settings to explore its polymerization behavior and potential applications in new materials science. Its properties are studied to understand how it can be integrated into innovative products and processes.
Used in Coatings and Adhesives:
2-(methylthio)ethyl acrylate is used as a component in the formulation of coatings and adhesives, where its polymerization properties contribute to the development of durable and high-performance products. Its inclusion in these formulations can enhance the bonding strength and resistance to environmental factors.
Used in Personal Protective Equipment:
Given its classification as a skin and eye irritant, 2-(methylthio)ethyl acrylate is also relevant in the development of personal protective equipment designed to safeguard workers from exposure to such chemicals. This includes the creation of gloves, masks, and other protective gear that can effectively minimize contact with hazardous substances.

InChI:InChI=1/C6H10O2S/c1-3-6(7)8-4-5-9-2/h3H,1,4-5H2,2H3

Upstream product

• 5271-38-5 2-methylmercapto-ethanol 
• 814-68-6 acryloyl chloride 
• 79-10-7 acrylic acid 

Relevant academic research and scientific papers

Enzymatically Degassed Surface-Initiated Atom Transfer Radical Polymerization with Real-Time Monitoring

Polymer brush coatings are frequently prepared by radical polymerization, a notoriously oxygen sensitive process. Glucose oxidase (GOx) can inexpensively enable radical polymerization in solution by enzymatically consuming oxygen as it oxidizes glucose. Here, we report the growth of polymeric brushes using GOx-assisted atom transfer radical polymerization (ATRP) from a surface while open to air. Specifically, we grew a set of biomedically relevant polymer brushes, including poly(oligo(ethylene glycol) methacrylate) (POEGMA), poly(2-dimethylaminoethyl methacrylate) (PDMAEMA), poly(sulfobetaine methacrylate) (PSBMA), and poly(2-(methylsulfinyl)ethyl acrylate (PMSEA). For each of these polymers, we monitored GOx-assisted and GOx-free ATRP reaction kinetics in real time using quartz crystal microbalance (QCM) and verified findings with localized surface plasmon resonance (LSPR). We modeled brush growth kinetics considering bimolecular termination. This model fit our data well (r2 > 0.987 for all samples) and shows the addition of GOx increased effective kinetic chain lengths, propagation rates, and reproducibility. We tested the antifouling properties of the polymer brush coatings against human blood plasma and were surprised to find that coatings prepared with GOx repelled more plasma proteins in all cases than their GOx-free counterparts.

Facile Light-Mediated Preparation of Small Polymer-Coated Palladium-Nanoparticles and Their Application as Catalysts for Alkyne Semi-Hydrogenation

A facile light-mediated preparation of small palladium nanoparticles (PdNPs) with a diameter of 1.3 nm and low dispersity by using low-priced and readily prepared photoactive polymers is presented. These polymers act as reagents for the photochemical reduction of Pd ions and they are also stabilizers for the PdNPs generated in situ. The PdNP–polymer hybrid materials prepared by this reliable approach are efficient hydrogenation catalysts that show high activity and Z-selectivity in the semi-hydrogenation of alkynes. These PdNP–catalyst hybrid materials can be readily recycled and reused up to five times.